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废旧纸塑铝复合包装物及其二次固废的炭化回收研究

Research on Carbonization and Recovery of Waste Paper-Plastic-Aluminum Composite Packaging and Its Secondary Solid Waste

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【作者】 陈俊荣倪尔灵张宏斌刘文贵曹长林张健薛珲肖荔人

【Author】 CHEN Jun-rong;NI Er-ling;ZHANG Hong-bin;LIU Wen-gui;CAO Chang-lin;ZHANG Jian;XUE Hun;XIAO Li-ren;College of Environmental and Resource Sciences·College of Carbon Neutral Modern Insustry,Fujian Normal University;Engineering Research Center of Polymer Green Recycling of Ministry of Education;Fujian Key Laboratory of Pollution Control & Resource Reuse;Fujian Academy of Environmental Sciences;Fujian Key Laboratory of Environmental Engineering;

【通讯作者】 曹长林;

【机构】 福建师范大学环境与资源学院,碳中和现代产业学院聚合物资源绿色循环利用教育部工程研究中心福建省污染控制与资源循环利用重点实验室福建省环境科学研究院福建省环境工程重点实验室

【摘要】 直接分离再生是废旧纸塑铝复合包装物常用手段之一,其过程会产生由残余纸浆碎屑、聚乙烯薄膜与铝膜组成的二次固废。采用热解炭化技术研究废旧纸塑铝复合包装各组分及二次固废的热分解特性及成炭规律。结果表明:炭化温度为550~700℃下,铝箔可从废旧复合包装物及其二次固废中分离回收。二次固废显示聚乙烯薄膜为主的热分解特性,随着炭化温度的提高,炭产率下降,无序结构比例增加,纤维结构被破坏,孔结构增多。炭化温度为600℃下,废旧复合包装物炭化产率为23.70%,比二次固废炭产率高,但二次固废的铝产率(35.41%)高于废旧复合包装物的铝产率(12.79%)。

【Abstract】 Direct separation and regeneration is one of the common methods for waste paper-plastic-aluminum composite packaging.This process generates secondary solid waste consisting of residual pulp debris,polyethylene film,and aluminum film.The pyrolysis carbonization technology was used to study thermal decomposition characteristics and charring law of each component of waste paper-plastic-aluminum composite packaging and secondary solid waste.The results show that when carbonization temperature is 550~700 ℃,aluminum foil can be separated and recovered from waste composite packaging and its secondary solid waste.The secondary solid waste shows thermal decomposition characteristics of polyethylene film.With the increase of carbonization temperature,carbon yield decreases,proportion of disordered structure increases,fiber structure is destroyed,and pore structure increases.When carbonization temperature is 600 ℃,carbonization yield of waste composite packaging is 23.70%,which is higher than that of secondary solid waste carbon,but aluminum yield of secondary solid waste(35.41%) is higher than that of waste composite packaging(12.79%).

【基金】 国家重点研发计划项目(2019YFC1908200);福建省科技计划项目(2022R1015001);福州市科技重大”揭榜挂帅“项目(2021-ZD-283)
  • 【文献出处】 塑料科技 ,Plastics Science and Technology , 编辑部邮箱 ,2023年10期
  • 【分类号】X705
  • 【下载频次】2
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