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气化细渣和煤掺烧氮氧化物和二氧化硫排放特性研究

Study on emission characteristics of NOx and SO2 from co-firing of fine gasification slag and coal

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【作者】 孙晓慧方梦祥匡建平王勤辉陈毅烈曾伟强郭伟岑建孟罗春桃

【Author】 SUN Xiao-hui;FANG Meng-xiang;KUANG Jian-ping;WANG Qin-hui;CHEN Yi-lie;ZENG Wei-qiang;GUO Wei;CEN Jian-meng;LUO Chun-tao;State Key Laboratory of Clean Energy Utilization, Zhejiang University;Qingshan Lake Energy Research Base, Zhejiang University, Qingshan Lake Science and Technology City;Ningxia Shenyao Technology Co.Ltd;

【机构】 浙江大学能源清洁利用国家重点实验室浙江大学青山湖能源研究基地宁夏神耀科技有限责任公司

【摘要】 气化细渣热值低、水分高,难以独立稳定燃烧,因此通常将其和热值较高的燃料进行掺混实现燃烧利用。为研究气化细渣和煤掺烧过程中NOx和SO2的排放特性,利用管式炉燃烧污染物测试系统,在空气气氛下,使用不同比例的气化细渣和烟煤进行掺烧实验,对燃烧污染物的释放量进行实时监测,并计算燃烧污染物的释放总量。通过实验发现:温度是影响NOx、SO2排放量的重要因素,在高温工况下,NO、SO2的释放量显著提高,NO2、N2O的释放量显著降低。燃料中挥发分的含量与NO2、N2O的释放量有着密切关系,煤中挥发分含量较高,NO2、N2O的释放量也相对较高。整体NO2、N2O的释放量远小于NO的释放量,NOx排放以NO为主。随气化细渣掺烧比例增大,NO、SO2释放量降低。因此,通过与煤掺烧可以实现气化细渣的稳定低污染燃烧。

【Abstract】 Fine gasification slag has low calorific value and high moisture content, which makes it difficult to burn independently and stably.Therefore, it is usually blended with fuels of higher calorific value to achieve combustion utilization. In order to study the emission characteristics of NOx and SO2 from co-firing of fine gasification slag and coal, in this paper, a tube furnace combustion pollutant test system was used to conduct co-combustion experiments firing fine gasification slag and coal of different ratios under air atmosphere, while the release of combustion pollutants were monitored in real-time and the total release was calculated. The experiment demonstrates that temperature is an important factor affecting NOx and SO2 emissions. At high temperature, the release of NO and SO2 is significantly increased and the release of NO2 and N2O is significantly reduced. The content of volatile matter in fuel has a close relationship with NO2 and N2O release. Coal has higher volatile matter, so the release of NO2 and N2O is relatively high. The overall release of NO2 and N2O is much smaller than that of NO. The main NOx emission is NO. With the increase of the proportion of fine gasification slag, the release amount of NO and SO2 decreases. Therefore, fine gasification slag co-firing with coal can achieve stable and low-pollution combustion.

【关键词】 气化细渣烟煤掺烧NO_xSO2
【Key words】 fine gasification slaganthracite coalco-firingNO_xSO2
【基金】 中央高校基本科研业务费专项资金资助(2022ZFJH004)
  • 【文献出处】 能源工程 ,Energy Engineering , 编辑部邮箱 ,2023年03期
  • 【分类号】X701;TQ534
  • 【下载频次】12
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