【摘要】 针对CO还原NO动力学反应的发展现状，本文分析了煤中灰物质的主要成分（Fe₂O₃,CaO/MgO,Al₂O₃,SiO₂等）对此还原反应的催化活性特征，同时考虑温度和压强对反应转化率的影响，本文进一步确定了NO-CO还原反应动力学参数.结果表明，相同实验条件下，灰成分的存在有效降低了还原反应过程中的活化能，从而增加了反应效率，实现了高效低氮燃烧.其中Fe₂O₃催化活性尤为显著，CaO对NO的转化率随温度的升高先增大后减小，而SiO₂和Al₂O₃在反应中视为惰性组分.经综合分析，这种从源头上减少NO_x排放含量的催化还原脱硝方法具有很好的应用前景.更多还原

【Abstract】 Based on the development status of kinetic reaction of CO reduction of NO,this paper analyzed the catalytic activity characteristics of the main components of coal ash（Fe₂O₃,CaO/MgO,Al₂O₃,SiO₂,etc.）for this reduction reaction.Meanwhile, as temperature and pressure affect the reaction conversion, it also further determined the kinetic parameters of NO-CO reduction reaction.The results show that under the same experimental conditions, ash can effectively reduce the activation energy in the reduction reaction process, thus increasing the reaction efficiency and achieving high efficiency and low nitrogen combustion.The catalytic activity of Fe₂O₃ is particularly significant, and the conversion rate of CaO for NO first increases and then decreases with the increase of temperature, while SiO₂ and Al₂O₃ are treated as inert components in the reaction.The comprehensive analysis indicates that the catalytic reduction denitrification method has very bright application prospects.更多还原