【摘要】 储能行业和新能源汽车的爆发式增长要求对锂离子电池的老化行为尤其是电池的寿命行为有更加深入的了解.准确地预测电池在各种工作条件下的使用寿命有助于优化电池的实际运行条件和延长电池的使用寿命,最终达到降低电池生命周期内总成本的目的.加速老化是一种经济高效的产品寿命评价方法,可以在短时间内获得大量的电池老化信息,快速预测锂离子电池在各种工作应力下的寿命特征.然而,基于加速老化进行电池寿命预测的前提是电池老化机理的一致性.本文综述了锂离子电池内各部件的老化机理和应力加速条件下的电池衰退机制以及相应的老化模式,为评价电池老化机理的一致性提供了参考.此外,本文还介绍了一些基于加速老化的电池寿命经验预测模型并为今后锂离子电池的加速老化研究提供了一些建议.更多还原

【Abstract】 The exponential growth of stationary energy storage systems(ESSs) and electric vehicles(EVs) necessitates a more profound understanding of the degradation behavior of lithium-ion batteries(LIBs), with specific emphasis on their lifetime. Accurately forecasting the lifetime of batteries under various working stresses aids in optimizing their operating conditions, prolonging their longevity, and ultimately minimizing the overall cost of the battery life cycle. Accelerated aging, as an efficient and economical method,can output sufficient cycling information in short time, which enables a rapid prediction of the lifetime of LIBs under various working stresses. Nevertheless, the prerequisite for accelerated aging-based battery lifetime prediction is the consistency of aging mechanisms. This review, by comprehensively summarizing the aging mechanisms of various components within LIBs and the battery degradation mechanisms under stress-accelerated conditions, provides a reference for evaluating the consistency of battery aging mechanisms. Furthermore, this paper introduces accelerated aging-based lifetime prediction models and offers constructive suggestions for future research on accelerated lifetime prediction of LIBs.更多还原