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基于NiMoO4的超级电容器作为自充电储能器件的性能研究

High performance NiMoO4 based supercapacitor for durable self-charging energy storage device

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【作者】 杨希佳黄银王丽莹李雪松吕威

【Author】 YANG Xijia;HUANG Yin;WANG Liying;LI Xuesong;LYU Wei;Key Laboratory of Advanced Structural Materials, Changchun University of Technology;School of Materials Science & Engineering, Changchun University of Technology;

【通讯作者】 黄银;

【机构】 长春工业大学教育部先进结构材料重点实验室长春工业大学材料科学与工程学院

【摘要】 钼酸镍(NiMoO4)复合材料具有稳定的晶体构造、较高的导电性能,以碳布作为基底制备了NiMoO4@CC//Fe2O3非对称超级电容器,经过电化学测试表明,其具有不错的稳定性和良好的倍率性能,同时还有较高的功率密度,在功率密度为805μW·cm-2时,器件的能量密度是6.76μW·h·cm-2。此外,用石墨烯和硅橡胶制备了能够收集能量的摩擦纳米发电机(GO-TENG),通过测试发现,其开路电压可以稳定在100 V左右,短路电流大约为6μA,瞬时功率约为450μW,并且在长时间的测试中其性能没有下降,证明其具有良好的稳定性能。将两者组合在一起形成一个自供电装置,TENG收集的能量可以在超级电容器中储存,需要时对外部供电。

【Abstract】 The nickel molybdate(NiMoO4) composite material has stable crystal structure and high electrical conductivity. We prepared the NiMoO4@CC//Fe2O3 asymmetric supercapacitor on the basis of carbon cloth. The electrochemical test shows that it has good stability, good multiplier performance, and high power density. When the power density is 805 μW·cm-2, the energy density is 6.76 μW·h·cm-2. In addition, a friction nanogenerator(GO-TENG) was prepared using graphene and silicone rubber to collect energy. It was found that the open-circuit voltage, short-circuit current and instantaneous power of Go-TENG can be stabilized at about 100 V, about 6 μA and 450 μW, and the performance of Go-TENG is not decreased during the test, which proves that the good stability performance. Combining the two to form a self-powered device, the energy collected by the TENG can be stored in a supercapacitor to supply external power when needed.

【关键词】 NiMoO4超级电容器水热法自充电
【Key words】 NiMoO4supercapacitorhydrothermal methodself-charging
【基金】 国家自然科学基金青年基金(62004014)
  • 【文献出处】 长春工业大学学报 ,Journal of Changchun University of Technology , 编辑部邮箱 ,2023年02期
  • 【分类号】TM53
  • 【下载频次】111
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