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稀土掺杂卤化铅钙钛矿的制备、性能与辐射探测器
Rare EarthDoped Lead Halide Perovskites:Synthesis,Properties and RadiationDetectors
【摘要】 近年来卤化铅钙钛矿由于优异的半导体特性,在光伏器件、光电探测器等领域展现了优异的性能,成为材料科学的研究热点。稀土元素掺杂卤化铅钙钛矿是改善其性能的一种有效途径。本文从材料制备、掺杂结构与性能、辐射探测器等方面综述了稀土掺杂卤化铅钙钛矿的最新研究进展。稀土掺杂引入了新的发光中心和能级,产生新的发光特性、提高了钙钛矿晶体的结晶度和半导体性能。因此,稀土掺杂可以进一步提高卤化铅钙钛矿辐射探测器的性能。
【Abstract】 In recent years, lead halide perovskites have shown excellent performance in photovoltaic devices and photodetectors due to its excellent semiconductor properties and have become a hot spot in materials science.Doping rare earth elements is a promising way to improve the performances of lead halide perovskites. In this paper, we review the latest research progress of rare earths doped lead halide perovskite materials in the preparation, structures, properties, as well as radiation detectors. The doped rare earths introduce new luminescent centers and energy levels for new luminescence properties, improving the crystallinity and semiconductor performances of perovskite crystals. Therefore, rare earth doping can further improve the performance of lead halide perovskite radiation detectors.
【Key words】 lead halide perovskites; rare earth doping; photoluminescence; radiation detection;
- 【文献出处】 化学进展 ,Progress in Chemistry , 编辑部邮箱 ,2023年12期
- 【分类号】TB34
- 【下载频次】148