【摘要】 开发生物基平台化合物糠醛向1,5-戊二醇转化的绿色合成路线是减少人们对化石燃料依赖的有效途径。本工作设计制备了Pd-MoO₃/TiO₂双功能催化剂，通过N₂物理吸脱附，X射线光电子能谱（XPS），透射电镜（TEM）对其进行表征分析。对催化剂活性组分及载体进行筛选，优选出了Mo/Pd物质的量之比为1.5的催化剂，并对糠醛氢解反应路径进行了探究。实验结果表明，在150℃和H₂压力为3MPa的条件下，糠醛在2 h内可以完全转化，1,5-戊二醇的收率可以达到56%，催化剂重复使用5次活性无明显下降，稳定性良好。更多还原

【Abstract】 Developing a green synthetic route for the conversion of biobased platform compound furfural to 1,5-pentadiol is an effective way to reduce our dependence on fossil fuels. In this paper, Pd-MoO₃/TiO₂ bifunctional catalyst was designed, prepared, and characterized by N₂ physical adsorption and desorption,X-ray photoelectron spectroscopy（XPS） and transmission electron microscope（TEM）. The active components and support of the catalyst were screened, the catalyst with the Mo/Pd atomic number ratio of 1.5 was selected, and the hydrogen hydrolysis reaction path of furfural was explored. The results showed that the furfural could be completely transformed within 2 h under the condition of 150 ℃ and H₂ pressure of 3 MPa. The yield of 1,5-pentadiol could reach 56%. The activity of the catalyst had no obvious decrease after repeated use for 5 times.更多还原