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构建基于MOF-303的石英晶体微天平用于低湿度传感
Construction of MOF-303-based quartz crystal microbalance for low humidity sensing
【摘要】 通过简单的溶剂热法制备了铝基金属有机骨架MOF-303材料。利用X射线衍射仪、扫描电子显微镜、傅里叶变换红外光谱仪、全自动比表面积和孔隙度分析仪对MOF-303材料的结构进行了表征。对以MOF-303材料构建的石英晶体微天平传感器进行湿度敏感性能测试,结果表明,基于MOF-303材料的传感器在较宽的湿度范围内(3.39%~97.9%RH)表现出优异的湿敏性能,尤其是在3.39%RH低湿度条件下具有高达3 200 Hz的响应值,在极低湿度环境检测方面显示出应用潜力。此外,还对MOF-303材料的湿度敏感机制进行了探究。
【Abstract】 Aluminum based metal-organic framework MOF-303 was prepared by a facile solvothermal method. The structure characteristics of MOF-303 were investigated by X-ray diffractometer, scanning electron microscope, Fourier transform infrared spectrometer, and automatic specific surface area and porosity analyzer.Aquartz crystal microbalance sensor based on MOF-303 was tested for humidity sensing properties. The experimental results showed that MOF-303 sensor had an excellent sensing property over a wide humidity range(3.39% to 97.9% RH). Especially, the MOF-303 sensor exhibited a response value up to 3 200 Hz at 3.39% RH, providing an application potential in the detection of extremely low humidity environment. In addition, the humidity sensing mechanism of MOF-303 was further explored.
【Key words】 quartz crystal microbalance; metal-organic framework; MOF-303; low humidity sensor; sensing mechanism;
- 【文献出处】 黑龙江大学自然科学学报 ,Journal of Natural Science of Heilongjiang University , 编辑部邮箱 ,2023年06期
- 【分类号】TB34;TP212
- 【下载频次】37