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Ti元素对激光金属沉积Nb-Mo-Ta-W高熵合金缺陷的影响
Effect of Ti on defects in Nb-Mo-Ta-W high-entropy alloy prepared by laser metal deposition
【摘要】 采用激光金属沉积工艺对成分重组设计后的Nb-Mo-Ta-W系难熔高熵合金进行成形制备,利用X射线衍射仪和扫描电子显微镜对(NbMoTa)90W10和(NbMoTaTi)90W10两种高熵合金的相结构、缺陷与微观组织进行了表征分析,并通过多功能力学试验机对两种合金进行室温拉伸性能测试。结果表明:(NbMoTa)90W10和(NbMoTaTi)90W10两种高熵合金均为单相体心立方结构;Ti元素在Nb-Mo-Ta-W系合金中的晶界处形成了“液态薄膜”,可实现对沿晶裂纹的良好抑制;冶金缺陷的减少以及Ti元素引入的晶格畸变效应,(NbMoTaTi)90W10高熵合金的室温力学性能提升,屈服强度达到1156 MPa。
【Abstract】 The Nb-Mo-Ta-W series refractory high-entropy alloys with composition recombination design were manufactured by laser metal deposition process. The phase structure, defects and microstructure of(NbMoTa)90W10 and(NbMoTaTi)90W10 highentropy alloys were characterized and analyzed by X-ray diffraction and scanning electron microscope. The tensile properties of the two alloys were tested at room temperature by multifunctional mechanical testing machine. The results showed that both(NbMoTa)90W10 and(NbMoTaTi)90W10 high-entropy alloys are single-phase body centered cubic structures. Ti element forms a "liquid film" at the grain boundaries in Nb-Mo-Ta-W series alloy, which can effectively suppress intergranular cracks. Due to the reduction of metallurgical defects and the lattice distortion effect, the mechanical property of( NbMoTaTi) 90W10 high-entropy alloy at room temperature is improved, and the yield strength reaches 1156 MPa.
【Key words】 laser metal deposition; refractory high-entropy alloy; liquid film; metallurgical defects;
- 【文献出处】 航空材料学报 ,Journal of Aeronautical Materials , 编辑部邮箱 ,2023年04期
- 【分类号】TG139;TG665
- 【下载频次】14