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表面喷涂制备LiOH/PP无纺布复合材料的结构及性能研究

Structure and properties of LiOH/PP non-woven composite materials prepared by surface spraying

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【作者】 徐威陈龙孙俊芬

【Author】 XU Wei;CHEN Long;SUN Junfen;State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University;

【通讯作者】 陈龙;孙俊芬;

【机构】 东华大学纤维材料改性国家重点实验室

【摘要】 将含表面活性剂脂肪醇聚氧乙烯醚(AEO-9)的氢氧化锂(LiOH)水溶液喷涂在聚丙烯(PP)无纺布表面,并通过真空干燥的方式制备LiOH/PP无纺布复合材料,研究了不同AEO-9浓度及喷涂时间对复合材料负载结构、透气性及二氧化碳(CO2)吸附性能的影响。结果表明:添加少量的AEO-9可促进LiOH溶液在PP无纺布表层形成负载结构;AEO-9浓度增加,复合材料表层LiOH负载量明显减少,AEO-9浓度较低时复合材料的透气性好;喷涂时间延长,复合材料LiOH负载量增加,透气率下降;在LiOH浓度为100 g/L条件下,AEO-9浓度为0.2 g/L、喷涂时间为7 s时,复合材料单面LiOH负载量达到102.8 mg,透气率为715.51 mm/s, CO2吸附平衡时间约180 s, CO2吸附量为2.39 mg/cm2,CO2吸附效率达49.9%,具有较好的透气性和CO2吸附性能,优于国内商业化产品。

【Abstract】 Lithium hydroxide/polypropylene(LiOH/PP) non-woven composite materials were prepared by spraying LiOH aqueous solution containing fatty alcohol polyoxyethylene ether(AEO-9) surfactant onto the surface of PP non-woven fabric prior to vacuum drying. The effects of different concentrations of AEO-9 and spraying time on the loading structure, permeability and carbon dioxide(CO2) adsorption property of composite materials were studied. The results showed that adding a small amount of AEO-9 can promote the formation of a loading structure of LiOH solution on the surface of PP non-woven fabric; the LiOH loading capacity on the surface of the composite materials significantly decreased as the concentration of AEO-9 increased, and the permeability of the composite materials was good at relatively low concentrations of AEO-9; the LiOH loading capacity of the composite materials increased and the air permeability decreased with the prolongation of spraying time; and the composite materials had a LiOH loading capacity of 102.8 mg on one side of composite material, permeability of 715.51 mm/s, CO2 adsorption equilibrium time about 180 s, CO2 adsorption capacity of 2.39 mg/cm2 and CO2 adsorption efficiency of 49.9% under the condition of a LiOH concentration of 100 g/L, AEO-9 concentration of 0.2 g/L and spraying time of 7 s, indicating good permeability and CO2 adsorption property which was superior to those of commercial products in China.

  • 【文献出处】 合成纤维工业 ,China Synthetic Fiber Industry , 编辑部邮箱 ,2023年06期
  • 【分类号】TB332
  • 【下载频次】5
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