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CaMoO4:Ce/Tb发光材料的制备与性质研究

Preparation and Properties of CaMoO4: Ce/Tb Luminescent Materials

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【作者】 罗雨王聪刘程成王蕊金锐张艺

【Author】 LUO Yu;WANG Cong;LIU Cheng-cheng;WANG Rui;JIN Rui;ZHANG Yi;School of Chemisty and Chemical Engineering, Suzhou University;

【通讯作者】 张艺;

【机构】 宿州学院化学化工学院

【摘要】 采用燃烧法成功合成了CaMoO4:Ce/Tb发光材料,研究了不同Tb3+/Ce3+摩尔比对样品发光性能的影响。利用扫描电子显微镜(SEM)、X-射线衍射(XRD)、荧光光谱(FS)对材料结构及性能进行了表征。结果表明,当nTb∶nCe为1∶3时,样品的形貌最佳,合成的CaMoO4样品XRD图谱衍射峰及强度与标准卡号JCPDS 29-0351基本一致,在295 nm波长激发下,样品的发射光谱在403 nm和450 nm处出现较强发射峰,当nTb∶nCe为1∶2时,材料发光强度最大。

【Abstract】 CaMoO4:Ce/Tb luminescent materials were prepared using combustion method. The effect of Tb3+/Ce3+ion molar ratios on luminescent performance of the sample were investigated. The structure and luminescence properties of the materials were characterized using X-ray diffractor(XRD), scanning electron microscope(SEM), and fluorescence spectrometer(FS). the results showed that when nTb∶nCe was 1∶3, the samples had the best morphology, the diffraction peaks and intensity of the XRD spectrum of the synthesized CaMoO4 sample were consistent with the standard card number JCPDS 29-0351, with the optimal excitation at 295 nm, the emission peaks of the material were located at 403 nm and 450 nm, when nTb∶nCe was 1∶2, the luminescent intensity of the materials was strongest.

【关键词】 CaMoO4Ce/Tb发光材料
【Key words】 Ca(MoO4Ce/Tbluminescent materials
【基金】 安徽省高校学科(专业)拔尖人才学术资助项目:gxbjZD2020090;宿州学院环境监测技术研究所项目资助(2022YKF05、2022YKF31、2022YKF32);宿州学院科研发展基金(2021fzjj08);安徽省教育厅项目(KJ2021A1114)
  • 【文献出处】 广州化工 ,Guangzhou Chemical Industry , 编辑部邮箱 ,2023年17期
  • 【分类号】TB34
  • 【下载频次】5
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