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CsPbX3QDs@MOFs复合材料的研究综述

Introduction to Perovskite Quantum Dots and Metal-Organic Frameworks and the Development of Composites

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【作者】 赖妞黄启强张秦阳张博文王娟杨杰王茺杨宇王荣飞

【Author】 LAI Niu;HUANG Qi-qiang;ZHANG Qin-yang;ZHANG Bo-wen;WANG Juan;YANG Jie;WANG Chong;YANG Yu;WANG Rong-fei;College of Materials and Energy,Yunnan University;

【通讯作者】 王荣飞;

【机构】 云南大学材料与能源学院

【摘要】 全无机钙钛矿量子点CsPbX3(QDs)(X=Cl、 Br、 I)具有可覆盖整个可见光区(400~700 nm)的发射,单一发光峰较窄,量子效率较高,其发射波长和带隙可通过调节CsPbX3中卤素原子X来实现调控。因CsPbX3优异的光学特性而被广泛应用于显示领域,然而其稳定性较差等问题阻碍其进一步的应用。金属有机框架(MOFs)是一种多孔性的框架结构,因其独特的多孔结构,永久的孔隙率而作为一种基质载体来提高材料的稳定性。MOFs将QDs限制在主体内部不仅可以保护它们免受外部环境的刺激,使它们彼此隔离而不团聚,而且还可以实现各种新的特性和应用。将QDs限制在MOFs中所得的复合材料(CsPbX3 QDs@MOFs)具有比CsPbX3 QDs更优异的光学特性以及对周围环境更好的稳定性,复合材料(CsPbX3 QDs@MOFs)在光电器件,传感器以及加密与防伪领域有着广泛的应用。该综述首先介绍了CsPbX3 QDs相关结构、制备、光学性能和应用,以及现存问题。例如在毒性、稳定性、阴离子交换等方面及相应解决方法;其次介绍了MOFs结构、制备、特性及应用等相关内容;并对介绍复合材料CsPbX3 QDs@MOFs的制备、光学特性、应用,例如在白光二极管(WLEDs)、防伪和加密、用作催化剂、远程型白光发射器件中的应用,并实现了宽色域应用,验证了这些新型发光复合材料在背光显示应用中具有很大的应用前景。对复合材料CsPbX3 QDs@MOFs现阶段存在一些问题和需要改进方面提出一些见解,对下一步进行复合材料方向提供一些思路并对研究前景进行了展望。

【Abstract】 All-inorganic perovskite quantum dots CsPbX3(QDs)(X=Cl, Br, I) have a luminescence that can cover the entire visible light region(400~700 nm). A single luminescence peak is narrow and has a high quantum efficiency. Their emission wavelength and band gap can be regulated by regulating the halogen atom X in CsPbX3. CsPbX3 is widely used in the display field due to its excellent optical properties. However, it hinders its further applications. Metallic-organic framing(MOFs) are porous frame structures that serve as a matrix carrier to improve material stability due to their unique porous structure and permanent porosity. MOFs restricting QDs inside the subject can not only protect them from the external environment, isolating them from each other without reunion, but also realize various new features and applications. Composites(CsPbX3 QDs @ MOFs) that restrict QDs to MOFs have better optical properties than CsPbX3 QDs and better stability to the surrounding environment. Composites(CsPbX3 QDs@MOFs) have many applications in optoelectronic devices, sensors, encryption, and anti-counterfeiting. The review begins with the CsPbX3 QDs correlation structures, preparation, optical properties, applications, and existing problems. For example, in toxicity, stability, anion exchange and the corresponding solution, the structure, preparation, characteristics, and application of MOFs and further, the application of CsPbX3 QDs@MOFs, such as white light diodes(WLEDs), security and encryption, used as catalyst, remote white light transmitter, and realize the wide gamut application, verify these new composite applications in backlight display. This paper presents some problems and needs for improvement in the composite CsPbX3 QDs@MOFs, provides some ideas on the next direction of the composite materials, and makes prospects for the research prospect.

【基金】 国家自然科学基金项目(11804295,62064013);云南省自然科学基金项目(2019FB130)资助
  • 【文献出处】 光谱学与光谱分析 ,Spectroscopy and Spectral Analysis , 编辑部邮箱 ,2023年11期
  • 【分类号】TB332
  • 【下载频次】72
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