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生物质热解产物强化海砂矿选择性还原-磁选分离

Biomass pyrolysis product-enhanced selective reduction-magnetic separation of iron sand

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【作者】 黄柱成舒阳李屹鑫唐婷婷谢晨曦

【Author】 Huang Zhucheng;Shu Yang;Li Yixin;Tang Tingting;Xie Chenxi;School of Minerals Processing and Bioengineering, Central South University;

【通讯作者】 黄柱成;

【机构】 中南大学资源加工与生物工程学院

【摘要】 以清洁、碳中性、高活性、可再生的生物质作为还原剂,通过密封性气塞限制热解产物的逃逸,对海砂矿内配生物质直接还原行为进行了研究,研究表明,限制生物质热解产生热解产物(CO、H2、CO2、H2O、Cx Hy Oz)的逃逸,在反应罐内迅速形成了60 kPa的压力,有利于H2、CO的参与还原。其中焦油具有更高的活性,且保障了后期H2的来源,促进了海砂矿的低温快速还原。在还原温度1 120℃、还原80 min的条件下,可获得金属化率为97.81%、铁回收率为97.81%的铁粉,以及TiO2回收率为69.98%和V2O5回收率59.93%的富钛渣。

【Abstract】 Using clean, carbon neutral, highly reactive and renewable biomass as a reducing agent, limiting the escape of pyrolysis products by hermetic gas plugs, the direct reduction behavior of the biomass allotted within the iron sand was studied. The results show that a pressure of 60 kPa is rapidly developed in the reaction tank as a result of limiting the escape of pyrolysis products(CO、H2、CO2、H2O 、Cx Hy Oz) from biomass pyrolysis, which facilitates the participation of H2, CO in the reduction. The tar has higher activity and guarantees the source of H2 in the later stage, which promotes the rapid reduction of iron sand at low temperature. Under the conditions of reduction temperature of 1 120 °C and reduction for 80 min, the iron powder with 97.81% metallization and 97.81% Fe recovery can be obtained, as well as the titanium-rich slag with a TiO2 recovery of 69.98% and a V2O5 recovery of 59.93%.

【基金】 国家自然科学基金资助项目(52174330)
  • 【文献出处】 钢铁钒钛 ,Iron Steel Vanadium Titanium , 编辑部邮箱 ,2023年03期
  • 【分类号】TD951;TD924
  • 【下载频次】10
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