【摘要】 利用无机铜盐与5-（异烟酰胺基）间苯二甲酸,通过溶剂热合成法制备了一种新的金属有机骨架材料[Cu(C₁₄H₇N₂O₅)]·5H₂O·DMF;通过单晶X射线衍射（SCXRD）、热重分析（TG）、傅里叶变换红外光谱（FTIR）及气体吸附测试表征了该化合物的微观结构和基本物理化学性质.SCXRD分析结果表明,该化合物具有由Kagome层状结构组成的三维结构;N₂等温吸附-脱附测试结果表明,该化合物具有889.21 m²/g的BET比表面积和永久孔隙;理想吸附溶液理论（IAST）计算结果表明,该化合物对等摩尔CO₂/CH₄混合气体的分离比为5.52,说明该化合物能够有效分离CO₂/CH₄混合气体.更多还原

【Abstract】 A novel metal-organic framework,[Cu(C₁₄H₇N₂O₅)]·5H₂O·DMF,was synthesized by solvothermal method with inorganic copper salt and 5-（isonicotinamide） mbenzoic acid as starting materials.The microstructure and basic physical and chemical properties of the compound were characterized by means of single crystal X-ray diffraction（SCXRD）,thermogravimetric analysis（TG）,Fourier transform infrared spectroscopy（FTIR）,as well as gas adsorption and separation.Single crystal diffraction analysis showed that the compound has a 3D structure consisting of Kagome layered structure.Nitrogen isothermal adsorption-desorption test showed that the compound has a high BET surface area of 889.21 m²/g and permanent porosity.The gas separation ratio of the compound is calculated to be 5.52 by the ideal adsorbed solution theory（IAST）,indicating that the compound could effectively separate CO₂/CH₄ gas.更多还原