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基于相图低成本高温混合熔盐的配制及其热物性

Preparation of Low-Cost and High-Temperature Mixed Molten Salts Based on Phase Diagram and Their Thermophysical Property

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【作者】 王元聪桑丽霞

【Author】 WANG Yuancong;SANG Lixia;MOE Key Laboratory of Enhanced Heat Transfer and Energy Conservation, Beijing Key Laboratory of Heat Transfer and Energy Conversion, Beijing Municipality, Beijing University of Technology;

【通讯作者】 桑丽霞;

【机构】 北京工业大学传热强化与过程节能教育部重点实验室及传热与能源利用北京市重点实验室

【摘要】 基于相图计算,制备了三种碳酸盐-氯盐体系混合盐,利用同步热分析仪对所配制熔盐的熔点、潜热、初晶点、分解温度进行了测定,选出性能较好的混合盐,进而对其进行比热测试、热循环稳定性测试和蓄热成本计算。结果表明,0.18K2CO3-0.14Na2CO3-0.68NaCl混合盐具有较低的熔点、较高的潜热与分解温度和良好的热循环稳定性,与Li2CO3-Na2CO3-K2CO3混合熔盐相比具有更低的相变蓄热成本。

【Abstract】 Based on the phase diagram calculation,three mixed salts of carbonate-chloride salts were prepared,and the melting point,latent heat,freezing point and decomposition temperature of the prepared molten salts were measured by synchronous thermal analyzer to select out the mixed salts with better performance,followed by specific heat test,thermal cycle stability test and heat storage cost calculation.The results show that 0.18K2CO3-0.14Na2CO3-0.68NaCl mixed salt has a lower melting point,higher latent heat,higher decomposition temperature and good thermal cycle stability.This molten salt has a lower cost of phase change heat storage than the Li2CO3-Na2CO3-K2CO3mixed molten salt.

【基金】 国家重点研究计划(No.2018YFB1501002)
  • 【文献出处】 工程热物理学报 ,Journal of Engineering Thermophysics , 编辑部邮箱 ,2023年07期
  • 【分类号】TB321
  • 【下载频次】10
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