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Pd/MnO2@C催化剂对Cr(Ⅵ)液相催化加氢还原的研究

Study on Catalytic Hydrogenation Reduction of Cr(Ⅵ) by Pd/MnO2@C Catalyst

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【作者】 李电照曹玉红余代良刘潘新辰

【Author】 LI Dianzhao;CAO Yuhong;YU Dailiang;LIU Panxinchen;College of Ecology and Environment, Anhui Normal University;

【通讯作者】 曹玉红;

【机构】 安徽师范大学生态与环境学院

【摘要】 液体催化加氢技术是一种绿色经济无污染且能够有效还原去除水中污染物的技术。文章以贵金属Pd作为活性组分,以MnO2作为载体,通过在Pd/MnO2催化剂的表面包裹导电的碳层,形成碳包裹催化剂(Pd/MnO2@C)。通过ICP、XRD、SEM和Raman等表征技术手段对催化剂的组成和形貌进行表征,并系统地研究催化剂催化加氢还原Cr(Ⅵ)的性能。为了比较包裹碳催化剂的炭化温度影响,制备了一系列不同炭化温度的Pd/MnO2@C催化剂。结果表明Pd/MnO2@C-600催化剂对还原Cr(Ⅵ)具有良好的稳定性。

【Abstract】 Liquid catalytic hydrogenation is a green, economical and pollution-free technology that can effectively reduce and remove pollutants from water. In this paper, Pd as the active component and MnO2 as the carrier were used to wrap conductive carbon layer on the surface of Pd/MnO2 catalyst to form a carbon coated catalyst(Pd/MnO2@C). The composition and morphology of the catalyst were characterized by ICP, XRD, SEM and Raman characterization techniques. The performance of the catalyst to reduce Cr(Ⅵ) was systematically studied. A series of Pd/MnO2@C catalysts with different charring temperatures were prepared in order to compare the effect of charring temperature of the carbon encapsulated catalysts. The results of the catalyst showed that the Pd/MnO2@C-600 catalyst has a good stability for reducing Cr(Ⅵ).

【基金】 国家自然科学基金(41971175);安徽师范大学大学生创新创业训练计划项目(202110370063)
  • 【文献出处】 环境科学与技术 ,Environmental Science & Technology , 编辑部邮箱 ,2023年05期
  • 【分类号】X703
  • 【下载频次】6
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