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三亚市区臭氧污染变化特征及潜在源区分析

Characteristics and Potential Source Analysis of Ozone Pollution in Sanya City

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【作者】 符传博丹利佟金鹤徐文帅

【Author】 FU Chuanbo;DAN Li;TONG Jinhe;XU Wenshuai;Hainan Institute of Meteorological Science;Key Laboratory of South China Sea Meteorological Disaster Prevention and Mitigation of Hainan Province;Key Laboratory of Regional Climate-Environment Research for Temperate East Asia, Institute of Atmospheric Physics,Chinese Academy of Sciences;Hainan Research Academy of Environmental Sciences;

【机构】 海南省气象科学研究所海南省南海气象防灾减灾重点实验室中国科学院大气物理研究所东亚区域气候-环境重点实验室海南省环境科学研究院

【摘要】 该文基于三亚市区2个环境监测数据,结合气象观测资料,采用后向轨迹、聚类分析、潜在源区贡献因子算法和权重轨迹方法研究了三亚市日最大8 h平均(O3-8 h)质量浓度时空变化特征与气象因子的关系,以及O3传输路径和潜在贡献源区。结果表明,2014-2020年2个站点O3-8 h质量浓度变化趋势相反,河东站和河西站气候倾向率分别为0.303μg/(m3·a)和-0.405μg/(m3·a),趋势系数均没有通过信度检验。O3-8 h质量浓度逐月变化呈“V”型分布,最高值出现在10月;日变化表现为单峰型,峰值出现在15:00左右。平均气温在15~25℃之间,相对湿度为65%~80%,太阳总辐射为14~24 MJ/m2,日照时数为6~10 h/d,受6~12 m/s之间的东北风影响时,三亚市O3-8 h质量浓度会出现超标。多元回归分析表明,10 m平均风速、相对湿度、日照时数和平均气温是O3-8 h质量浓度的主控因子。秋季的内陆东北气流和沿海东北气流,春季的沿海东北气流,冬季短距离气流和东北气流影响下会出现三亚市O3-8 h质量浓度超标,超标率分别为13.61%、2.31%、1.44%、0.95%和2.76%;福建省、江西省和广东省是三亚市O3污染的主要贡献源区。

【Abstract】 Based on two environmental monitoring data and meteorological observational data in Sanya City,Hainan Province,spatiotemporal variation characteristics and meteorological influence of the O3-8 h (defined as the maximum 8 h average result) were analyzed using the backward trajectory simulation,cluster analysis,PSCF (potential source analysis function) and CWT (concentration weight trajectory) methods.The results show that the variations of O3-8 h at two stations in Sanya City is opposite from 2014 to 2020,and their climatic change rate were 0.303μg/(m3·a) and-0.405μg/(m3·a),respectively,which not passed the significance test.The monthly variation of O3-8 h shows a“V”-shaped distribution,with the maximum value occurred in October.The daily variation is unimodal,with a peak value around 15:00.The exceedance probability of O3-8 h concentrations was relatively high when the average temperature was around 15~25℃,relative humidity was between 65% and 80%,the total solar radiation ranged 14~24 MJ/m2,sunshine duration was between 6 h/d and 10 h/d,and wind speed of the northeast wind was between 6 to 12 m/s.Multiple regression analysis showed that 10 m average wind speed,relative humidity,sunshine duration and average temperature are the main dominate factors on O3-8 h.The inland northeast air flow and coastal northeast air flow in autumn,the coastal northeast air flow in spring and the short-distance air flow and northeast air flow in winter are likely to cause the above-normal O3-8 h concentration,and the exceeding rates are 13.61%,2.31%,1.44%,0.95%and 2.76%,respectively.Fujian,Jiangxi,and Guangdong provinces are the main sources to O3 pollution in Sanya City.

【基金】 国家自然科学基金项目(42065010,42141017);海南省重大科技计划项目(ZDKJ202007);海南省自然科学基金项目(422RC802,421QN0967);海南省院士创新平台科研项目(YSPTZX202143)
  • 【文献出处】 环境科学与技术 ,Environmental Science & Technology , 编辑部邮箱 ,2023年01期
  • 【分类号】X515
  • 【下载频次】31
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