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高密度块状钐铁氮磁体制备的研究进展

Research Progress on Fabrication of Sm-Fe-N Bulk Magnet with High Density

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【作者】 尉时通郑精武李荣耀卢卓玮黄珩朱俊辉乔梁蔡伟陈海波应耀李旺昌余靓车声雷

【Author】 Yu Shitong;Zheng Jingwu;Li Rongyao;Lu Zhuowei;Huang Heng;Zhu Junhui;Qiao Liang;Cai Wei;Chen Haibo;Ying Yao;Li Wangchang;Yu Jing;Che Shenglei;Research Center of Magnetic and Electronic Materials,College of Materials Science and Engineering,Zhejiang University of Technology;Hangzhou Chase Technology Co.,Ltd;

【通讯作者】 郑精武;

【机构】 浙江工业大学材料科学与工程学院磁电功能材料研究所杭州千石科技有限公司

【摘要】 钐铁氮化合物(Sm2Fe17N3)因具有比钕铁硼(Nd2Fe14B)更高的磁晶各向异性场和居里温度值及更少的稀土含量,成为新型稀土永磁材料研究热点。但是,由于钐铁氮在600℃左右会分解导致永磁性能消失,因此常规的高温烧结工艺并不适用于钐铁氮烧结磁体的制备,现只能将其与高分子材料复合用作塑磁材料,这就导致Sm2Fe17N3的磁学性能无法得到充分发挥。因此,开发低温成型工艺制备全金属高密度块状磁体是获取高性能钐铁氮磁体的关键。经过30多年的努力,科研人员已开发出多种制备钐铁氮磁体的低温快速成型工艺,并获得最大磁能积达到199 k J/m3的高性能磁体。本研究将从磁体的制备方法出发,总结当前块状钐铁氮磁体的研究现状及面临的问题,尤其针对不同成型方法出现矫顽力下降的现象提出分析,并对其今后的发展做出展望。

【Abstract】 Samarium iron nitrogen compound (Sm2Fe17N3) has become a research hotspot of new rare earth permanent magnet materials because of its high magnetic crystalline anisotropy field,Curie temperature and less rare earth content,compared with that of neodymium iron boron (Nd2Fe14B).However,since samarium iron nitrogen will decompose at 600℃,resulting in the disappearance of permanent magnetic properties,the conventional high-temperature sintering process is not suitable for the preparation of sintered samarium iron nitrogen magnets and it can only be compounded with polymer materials as plastic magnets,leading to the fact that the magnetic properties of Sm2Fe17N3 cannot be fully exerted.Therefore,the development of low-temperature forming process to prepare all-metal bulk magnets with high density is the key to obtain high-performance samarium-iron-nitrogen magnets.After more than 30years of hard work,researchers have developed a variety of low-temperature rapid prototyping processes to prepare samarium-iron-nitrogen magnets,and obtained high-performance magnets with a maximum magnetic energy product of 199 k J/m3.Starting from the preparation method of magnets,the current research status and problems of bulk samarium-iron-nitrogen magnets were summarized,particularly the phenomenon of coercivity decline in different fabrication methods was analyzed,and its future development was prospected.

【基金】 浙江省公益技术应用研究项目(LGG22E010010);国家自然科学基金青年项目(52101235);浙江省重点研发计划(2021C01172);浙江省教育厅科研项目(Y202043346)
  • 【文献出处】 稀有金属材料与工程 ,Rare Metal Materials and Engineering , 编辑部邮箱 ,2023年06期
  • 【分类号】TM273
  • 【下载频次】29
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