节点文献
泡沫镍原位负载双金属AlCo层状双氢氧化物纳米催化剂高效电催化析氧反应
In-Situ Bimetallic AlCo-Layered Double Hydroxide Nano-catalyst Supported on Foamed Nickel for Efficient Electrocatalysis of Oxygen Evolution Reaction
【摘要】 经一步水热法在泡沫镍(NF)上原位生长获得了 AlCo-LDH/NF(LDH=层状双氢氧化物)催化剂。基于 AlCo-LDH 的高表面积和良好相界面,催化剂表现出了优异的电催化析氧反应(OER)活性。在碱性介质中,当电流密度为 200 mA·cm-2时,AlCo3-LDH/NF催化剂具有419 mV的低过电位和50.04 mV·dec-1的低Tafel斜率。
【Abstract】 The AlCo-LDH/NF (layered double hydroxide, LDH) catalyst was obtained by in situ growth on nickel foam (NF) by a one-step hydrothermal method. Benefitting from the transition metal-based LDH, as-synthesized AlCo-LDH in-situ grown on nickel foam (NF) electrocatalyst exhibited outstanding oxygen evolution reaction (OER performance with an exceptionally low overpotential of 419 mV at 200 mA·cm-2current density in an alkaline electrolyte, an extremely small Tafel slope (50.04 mV·dec-1) and excellent durability, which is due to its high surface area and optimized phase interfaces.
【Key words】 layered double hydroxide; oxygen evolution reaction; cyclic voltammetry; nickel foam;
- 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2022年10期
- 【分类号】TQ116.21;TQ426
- 【下载频次】295