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脱硫石膏对微膨胀基层水泥性能与早期水化的影响

Effect of Desulfurized Gypsum on Properties and Early Hydration of Slight-expansive Road Base Cement

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【作者】 王亚楠赵德强曹亮宏刘超王中文赵立张文贵沈卫国

【Author】 WANG Ya-nan;ZHAO De-qiang;CAO Liang-hong;LIU Chao;WANG Zhong-wen;ZHAO Li;ZHANG Wen-gui;SHEN Wei-guo;School of Materials Science and Engineering,Wuhan University of Technology;State Key Laboratory of Silicate Materials for Architecture,Wuhan University of Technology;Poly Changda Engineering Co Ltd;

【通讯作者】 沈卫国;

【机构】 武汉理工大学材料科学与工程学院武汉理工大学硅酸盐建筑材料国家重点实验室保利长大工程有限公司

【摘要】 脱硫石膏产生量大利用率低,利用脱硫石膏制备了微膨胀基层水泥,并通过扫描电镜、XRD、TG-DTG研究了脱硫石膏对基层水泥性能及早期水化的影响。结果表明:脱硫石膏掺量为13%时,缓凝效果最佳;随着脱硫石膏掺量的增加,抗折及抗压强度呈现先增加后降低的趋势,且在9%处达到最大值;脱硫石膏掺量增加可促进早期钙矾石的形成,但对水泥浆体中Ca(OH)2的结晶析出有一定抑制作用;膨胀率随着龄期的延长及脱硫石膏掺量的增加而增大,高掺量脱硫石膏基层水泥后期膨胀率的增量高于低掺量。

【Abstract】 In order to realize efficient and high value-added utilization of desulphurized gypsum and improve the performance of road base cement,this paper studied the influence of desulphurized gypsum on the performance and early hydration of micro-expansion road base cement with different dosage by scanning electron microscopy,XRD and TG-DTG.When the content of desulfurized gypsum is 13%,the retarding effect is the best.With the increase of desulfurized gypsum content,the flexural and compressive strength decrease and reach a maximum value at 9%.The addition of desulfurized gypsum can promote the formation of ettringite in early stage,but inhibit the crystallization of Ca(OH)2 in cement slurry to a certain extent.The increment of expansion rate of high content desulfurized gypsum base cement is higher than that of low content.

  • 【文献出处】 武汉理工大学学报 ,Journal of Wuhan University of Technology , 编辑部邮箱 ,2022年10期
  • 【分类号】TQ172.1
  • 【下载频次】24
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