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机械力化学制备单组分地聚物性能提升机制

Mechanism of performance enhancement of the one-part geopolymers prepared by mechanochemistry

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【作者】 吴文达; 沈妍燃; 王雪芳; 黄雷杰; 赵永华; 林镇;

【Author】 WU Wenda;SHEN Yanran;WANG Xuefang;HUANG Leijie;ZHAO Yonghua;LIN Zhen;School of Advanced Manufacturing, Fuzhou University;College of Civil Engineering, Fuzhou University;CSCEC Strait Construction and Development Co.,Ltd.;Huahui Construction Engineering Group Co.,Ltd.;

【通讯作者】 王雪芳;

【机构】 福州大学先进制造学院; 福州大学土木工程学院; 中建海峡建设发展有限公司; 华辉建工集团有限公司;

【摘要】 为考察机械力化学对单组分地聚物粉体的比表面积、粒度以及净浆抗压强度的影响,进行了机械力化学制备单组分地聚物的试验研究,并进行同配比条件下的简单混合对比试验,同时通过X射线衍射(XRD)、同步热分析(DTG)、傅里叶红外光谱(FTIR)等技术分析机械力化学的作用机制。研究结果表明:机械力化学制备单组分地聚物,其比表面积较简单混合有明显增大;机械力化学制备的单组分地聚物净浆不同龄期的抗压强度较简单混合制备均有较大提高。分析可得,机械力化学能够有效细化单组分地聚物粉体颗粒粒径,提高反应活性,促使反应更早发生,从而改善其宏观特性。研究成果能为机械力化学制备单组分地聚物的工程应用提供参考依据。

【Abstract】 To investigate the effect of mechanical activation on the specific surface area and particle size distribution of one-art geopolymer powder and the compressive strength of paste, the experimental study of one-part geopolymer prepared by mechanochemistry and the comparison test of simple blend under the same mix proportion were conducted.The experiments were conducted to investigate the effects of the two different preparation methods on the specific surface area of the powder and the compressive strength of the paste.The mechanism of mechanical activation was revealed by XRD,DTG,and FTIR techniques.The results showed that the specific surface area of the one-part geopolymer prepared by mechanical activation increased significantly compared with that of the simple blend.The compressive strength of the one-part geopolymer paste prepared by mechanochemistry at different ages increased significantly compared with that of the simple blend.From the analysis, it can be concluded that mechanochemistry can effectively refine the particle size of the one-part geopolymer powder, increase the reactivity, and promote the reaction to occur earlier, thus improving its macroscopic properties.The results of the study can provide a reference for the engineering application of the one-part geopolymer prepared by mechanochemistry.

【基金】 国家自然科学基金项目(51808124);绿色建筑材料国家重点实验室开放基金(2021GBM07);泉州市科技计划项目(2021C026R)~~
  • 【文献出处】 南昌大学学报(工科版) ,Journal of Nanchang University(Engineering & Technology) , 编辑部邮箱 ,2022年03期
  • 【分类号】TU528
  • 【下载频次】30
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