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高铁含量型CaO-FeO-ZnO-SiO2炉渣黏度研究

Viscosity of CaO-FeO-ZnO-SiO2 System Slag with High Iron Oxide Content

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【作者】 朱俊畅永锋谢锋

【Author】 ZHU Jun;CHANG Yong-feng;XIE Feng;Key Laboratory for Ecological Metallurgy of Multimetallic Mineral(Ministry of Education),Northeastern University;School of Metallurgy, Northeastern University;Key Laboratory for Recycling of Nonferrous Metal Resources(Shenyang);

【通讯作者】 畅永锋;

【机构】 东北大学多金属共生矿生态化冶金教育部重点实验室东北大学冶金学院沈阳市有色金属资源循环利用重点实验室

【摘要】 炉渣黏度对铅基固废熔炼过程的顺利进行具有重要影响,而炉渣黏度与炉渣结构存在内在联系。以CaO-FeO-ZnO-SiO2四元系合成渣为研究对象,采用熔体物性综合测定仪测定合成渣的黏度,在FeO/SiO2=1.5~2.4、CaO/SiO2=0.3~0.7、ZnO=5%~15%范围内探讨了炉渣黏度随温度组成变化的关系。结果表明,所研究的炉渣均为典型的碱性炉渣,其黏度曲线具有明显的熔化性温度。当CaO、FeO和ZnO的含量过高,造成SiO2小于24%时,黏度曲线的熔化性温度明显增大。适宜的炉渣组成为ZnO 11%、FeO/SiO2=1.8、CaO/SiO2=0.5。

【Abstract】 Suitable slag viscosity is vital for smooth operation of smelting lead-containing solid wastes, and the slag viscosity is intrinsically related to slag structure.Viscosities of synthetic slags were investigated for FeO-SiO2-CaO-ZnO system with a range of FeO/SiO2=1.5-2.4,CaO/SiO2=0.3-0.7,and ZnO=5%-15%.The experiment results show that all tested slags exhibit the property of basic type slag characterized by clear fusion temperature in the viscosity curves.Too much of CaO,FeO,and ZnO in slag would depress SiO2 content down below 24%,which cause a notable increasement of the slag fusion temperature.The proper slag composition is determined as ZnO 11%,FeO/SiO2=1.8,and CaO/SiO2=0.5.

【关键词】 火法冶炼黏度炉渣
【Key words】 pyrometallurgyviscosityslagleadzinc
【基金】 国家重点研发计划项目(2019YFC1907302)
  • 【文献出处】 有色金属(冶炼部分) ,Nonferrous Metals(Extractive Metallurgy) , 编辑部邮箱 ,2022年08期
  • 【分类号】TF812
  • 【下载频次】70
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