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浓硫酸预活化—浸出高铅锌含砷烟尘
Concentrated Sulfuric Acid Pre-activation and Leaching of Arsenic Containing Dust with High-Lead-Zinc Content
【摘要】 针对铅冶炼产出的高铅锌含砷烟尘成分复杂、难于处理的特点,采用浓硫酸预活化—浸出处理工艺,进行铅、锌的回收以及砷、镉等有害元素的脱除。考察预活化及浸出过程中各参数对烟尘浸出过程的影响。研究表明:当酸尘比为1 mL/g、预活化温度60℃、预活化时间2 h、硫酸浓度0.5 mol/L、液固比5 mL/g、浸出温度80℃、浸出时间2 h,搅拌速度400 r/min时,效果最佳,锌、砷、镉、铅的浸出率分别为98.64%、95.02%、95.26%和0.16%。
【Abstract】 Aiming at complex and difficult-to-handle characteristics of high-lead-zinc containing arsenic dust from lead smelting furnace, a concentrated sulfuric acid pre-activation leaching process was used to recover lead and zinc and remove harmful elements such as arsenic and cadmium.Effects of various parameters in pre-activation and leaching process on leaching of fume were investigated.The results show that leaching rate of zinc, arsenic, cadmium, and lead is 98.64%,95.02%,95.26% and 0.16%,respectively under the optimum conditions including ratio of acid to dust of 1 mL/g, pre-activation temperature of 60 ℃,pre-activation time of 2 h, sulfuric acid concentration of 0.5 mol/L,L/S of 5 mL/g, leaching temperature of 80 ℃,leaching time of 2 h, and stirring speed of 400 r/min.
【Key words】 lead smelting dust; pre-activation; leaching; zinc; arsenic;
- 【文献出处】 有色金属(冶炼部分) ,Nonferrous Metals(Extractive Metallurgy) , 编辑部邮箱 ,2022年05期
- 【分类号】X758
- 【下载频次】95