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时效时间对Zn-5.5Mg-0.4Ba-0.7Gd合金组织及性能的影响

Effect of aging time on microstructure and properties of Zn-5.5Mg-0.4Ba-0.7Gd alloy

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【作者】 刘敬福尹康鹿超超庄伟彬

【Author】 Liu Jingfu;Yin Kang;Lu Chaochao;Zhang Weibin;College of Materials Science and Engineering, Liaoning Technology University;

【机构】 辽宁工程技术大学材料科学与工程学院

【摘要】 对真空熔炼制备的Zn-5.5Mg-0.4Ba-0.7Gd合金在150℃分别时效2、4、8 h,研究时效时间对合金组织及性能的影响。结果表明,时效可以改善合金的微观结构,时效初期合金中的MgZn2相逐渐转化为Mg2Zn11相。电化学测试结果表明,时效4 h后合金耐腐蚀性能最佳,自腐蚀电位为-942.844 mV,自腐蚀电流密度为13.34μA/cm2,微孔电阻为1894Ω·cm2,电荷转移电阻为1613Ω·cm2。时效4 h后合金腐蚀产物主要由具有优良的生物相容性的磷酸锌(钙)、碳酸锌(钙)和氢氧化锌组成。

【Abstract】 Zn-5.5 Mg-0.4 Ba-0.7 Gd alloy prepared by vacuum melting was aged at 150 ℃ for 2, 4 and 8 h respectively. The effect of aging time on microstructure and properties of the alloy was studied. The results show that aging can improve microstructure of the alloy. At the beginning of aging, MgZn2 phase in the alloy gradually transforms into Mg2Zn11 phase. The electrochemical test results show that the alloy aged for 4 h has the best corrosion resistance, the self corrosion potential is-942.844 mV, and the self corrosion current density is 13.34 μA/cm2, the micropore resistance is 1894 Ω·cm2, and the charge transfer resistance is 1613 Ω·cm2. The corrosion products of the alloy aged for 4 h are mainly composed of zinc phosphate(calcium), zinc carbonate(calcium) and zinc hydroxide with excellent biocompatibility.

【基金】 辽宁省自然科学基金(201602356);辽宁省教育厅科学研究经费项目基础研究项目(LJ2019JL008)
  • 【文献出处】 金属热处理 ,Heat Treatment of Metals , 编辑部邮箱 ,2022年12期
  • 【分类号】TG146.13;TG156.92
  • 【下载频次】3
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