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Synthesis and Crystal Structure of a Copper(Ⅱ) Complex with Funnel-like Ligand Based on Calix[6]arene

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【Author】 WANG Yi-Feng;SHU Mou-Hai;School of Chemistry and Chemical Engineering,Frontiers Science Center for Transformative Molecules,Shanghai Jiao Tong University;

【通讯作者】舒谋海;

【机构】 School of Chemistry and Chemical Engineering,Frontiers Science Center for Transformative Molecules,Shanghai Jiao Tong University；

【摘要】 The preparation method of a funnel like ligand derived from calix[6]arene and tris(2-pyridyl-methyl)anime has been improved. The Cu(Ⅱ) complex was obtained and characterized by ESI-MS, EPR, UV-Vis spectra and crystallographic analysis. In the complex, a guest acetonitrile molecule is introduced into the cavity of the ligand host via the coordination with Cu(Ⅱ) center.更多还原

【Abstract】 The preparation method of a funnel like ligand derived from calix[6]arene and tris(2-pyridyl-methyl)anime has been improved. The Cu(Ⅱ) complex was obtained and characterized by ESI-MS, EPR, UV-Vis spectra and crystallographic analysis. In the complex, a guest acetonitrile molecule is introduced into the cavity of the ligand host via the coordination with Cu(Ⅱ) center.更多还原

【关键词】 Cu(Ⅱ) complex； crystal structure； calix[6]arene； host-guest interaction；
【Key words】 Cu(Ⅱ) complex； crystal structure； calix[6]arene； host-guest interaction；

【基金】 Financial support from the Natural Science Foundation of Shanghai (No. 19ZR1424900)

【文献出处】 Chinese Journal of Structural Chemistry ,结构化学(英文版) , 编辑部邮箱 ,2022年03期

【分类号】O641.4
【下载频次】10

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