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活性炭吸附饮用水中三卤甲烷的实验研究
Experimental study on adsorption of trihalomethane in drinking water by activated carbon
【摘要】 采用活性炭吸附方法控制饮用水中的三卤甲烷(THMs)。对筛选的活性炭进行动态和静态吸附实验。在ACL1,ACL2,ACY,ACM 4种活性炭中,椰壳活性炭ACL1对THMs的平衡吸附量最高;吸附行为更符合Freundlich经验模型。静态吸附实验结果表明,前1 h ACL1对THMs的吸附效率较高,4 h内达到吸附平衡,当温度为27~36℃时,温度变化对活性炭吸附THMs的影响较小;当THMs的初始浓度为200μg·L-1时,ACL1对THMs的去除率大于90%;ACL1对THMs的吸附效率依次为CHBr3>CHClBr2>CHCl2Br>CHCl3。动态吸附实验结果表明,当进水的THMs浓度为200μg·L-1时,出水THMs达到《生活饮用水卫生标准》(GB5749—2006)所需的最大吸附时长分别为:CHCl38.1 h,CHCl2Br 15.3 h,CHClBr215.6 h,CHBr316.5 h。
【Abstract】 To control the amount of trihalomethane (THMs) in drinking water,this study employs activated carbon as adsorbent to adsorb THMs.Experimental results show that coconut shell activated carbon ACL1 has higher equilibrium adsorption capacity for THMs.The static adsorption test showed that activated carbon ACL1 presented higher adsorption efficiency for THMs within 1 hour,and reached adsorption equilibrium within 4 h.It was found that,the temperature had little effect on the adsorption of THMs by activated carbon within the range of 27- 36℃;When the initial concentration of THMs was twice the limit value of national standard,the removal rate of THMs was higher than 90%.The best adsorption effect of coconut shell activated carbon ACL1 was on CHCl3,followed by CHCl2Br,CHClBr2 and CHBr3.The results of dynamic adsorption test showed that when the influent concentration of THMs were 200μg·L-1,the removal efficiency of THMs by the advanced treatment process meet the requirements of sanitary standard for drinking water (GB5749-2006).The adsorption effect of CHCl3,CHCl2Br,CHClBr2 and CHBr3 was consistent with the static adsorption test.The maximum adsorption time was 8.1,15.3,15.6 and 16.5 h,respectively.
【Key words】 coconut shell activated carbon; THMs; drinking water; adsorption;
- 【文献出处】 浙江大学学报(理学版) ,Journal of Zhejiang University(Science Edition) , 编辑部邮箱 ,2022年04期
- 【分类号】TU991.2
- 【下载频次】249