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K8[Fe(H2O)W11MnO39]/PANI/V2O5三元复合材料的制备、表征及光催化性能研究

Preparation and photocatalytic properties of ternary composite materials K8[Fe(H2O)W11MnO39]/PANI/V2O5

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【作者】 李英单秋杰陈林栾成钰

【Author】 LI Ying;SHAN Qiu-jie;CHEN Lin;LUAN Cheng-yu;College of Chemistry and Chemical Engineering, Qiqihar University;

【通讯作者】 单秋杰;

【机构】 齐齐哈尔大学化学与化学工程学院

【摘要】 本文运用静电自组装法合成了一种新型三元复合材料K8[Fe(H2O)W11MnO39]/PANI/V2O5,并采用IR、UV、XRD、XPS、SEM、氮气吸附等方法对其进行表征;然后,以龙胆紫为有机污染物进行光催化实验,对此三元复合催化剂的降解性能进行研究。结果表明:K8[Fe(H2O)W11MnO39]/PANI/V2O5已被成功复合,且仍然保持Keggin结构,稳定性能良好;在pH=2,龙胆紫C=5 mg·L-1,此催化剂用量为5 mg的条件下,其脱色率高达93.09%。可见,此复合催化剂具有优异的研究潜力和实用价值。

【Abstract】 The ternary composite K8[Fe(H2O)W11MnO39]/PANI/V2O5 was successfully prepared by electrostatic self-assembly method and characterized by IR,UV,XRD,XPS,SEM and N2 adsorption desorption.Then, its photocatalytic performance was discussed by degradation experiment with Gentian Violet as an organic pollutant.The results showed that K8[Fe(H2O)W11MnO39]/PANI/V2O5 was composited successfully of stable Keggin structure, its decolorization rate on dyes could reach to 93.09%under the initial concentration of gentian violet was 5 mg·L-1,pH=2 and the dosage of catalyst was 5 mg, which shows it has an excellent research potential and application value.

【基金】 黑龙江省教育厅科学技术研究项目(135209305)资助
  • 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2022年01期
  • 【分类号】TB332;TQ426;X791
  • 【下载频次】104
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