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一种部分水解聚丙烯酰胺的合成及性能评价

Synthesis and Property Evaluation of A Type of Partially Hydrolyzed Polyacrylamide

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【作者】 贾国豪朱嘉伟黄云崔莹周佳炜秦海望胡俊柯杨船王晓琴

【Author】 JIA Guo-hao;ZHU Jia-wei;HUANG Yun;CUI Ying;ZHOU Jia-wei;QIN Hai-wang;HU Jun;KE Yang-chuan;WANG Xiao-qin;College of Science, China University of Petroleum;CNPC Nanochemistry Key Laboratory, China University of Petroleum;

【通讯作者】 王晓琴;

【机构】 中国石油大学(北京)理学院中国石油大学(北京)CNPC纳米化学重点实验室

【摘要】 分别选用丙烯酰胺、丙烯酸、DMMAC作为主链单体、亲水单体及疏水单体,合成了一种三元共聚高相对分子质量部分水解聚丙烯酰胺,其具有较大的分子量,较好的化学稳定性和热稳定性。同时,该聚合物产品的固含量较高,可达51.35%。此聚合物溶液在0.0008416 g/mL的浓度下就具有较高的黏度,高达1.4614,是一种不错的增稠剂。本次研究所合成的聚合物材料的粘均分子量约为166万,分子量较大,具有优良的溶胀特性,在聚合物驱中应用前景广阔。

【Abstract】 Acrylamide, acrylic acid and DMMAC were selected as main chain monomers, hydrophilic monomers and hydrophobic monomers respectively to synthesize a ternary copolymerized partially hydrolyzed polyacrylamide with high relative molecular weight, which had a large molecular weight, good chemical stability and thermal stability.Polymer products had high solid content, 51.35%.The polymer solution had a high viscosity at a concentration of 0.0008416 g/mL,with a relative viscosity as high as 1.4614,so the product solution was a good thickener.The polyacrylamide had a viscosity average molecular weight of about 1.66 million, which had a large molecular weight and excellent swelling characteristics, and had a broad application prospect in polymer flooding.

【基金】 中国石油大学(北京)教改项目(2021-107:No:XM10720200034,No:XM10720180131);国家自然基金面上项目(No:51974339,No:51674270);国家重大专项(No:2017ZX05009-003);PetroChina勘探开发研究院项目(No:HX20201095)
  • 【文献出处】 广州化工 ,Guangzhou Chemical Industry , 编辑部邮箱 ,2022年14期
  • 【分类号】TQ317
  • 【下载频次】144
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