【摘要】 动力学信息作为化学动力学研究的关键因素，以反应速率常数形式呈现于速率方程组中，而如何估计反应体系的速率常数则是化学动力学研究的首要问题.通过深入分析反应微分方程组速率常数矩阵的结构性特征，借助于矩阵特征体系可以建立利用有限的实验反应路径估计动力学信息的方法.此方法不仅可以克服反应体系的高耦合性与高维度造成的计算困难，而且提供了描绘及预测反应体系宏观行为的几何视角.更多还原

【Abstract】 As a key factor in the study of chemical kinetics, the acquisition of kinetic information is the core of the study. By deeply analyzing the structural characteristics of the rate constant matrix of the reaction rate differential equations, the method of estimating the kinetic information with the matrix characteristic system under the background of limited experimental path data is realized. This analysis not only explains how to overcome the computational difficulties caused by the high coupling and high dimension of the reaction system, but also describes and predicts the macroscopic behavior of the reaction system from a geometric perspective.更多还原