【摘要】 采用分子构筑块策略设计合成了一个含萘基的直线型有机羧酸配体4,4′-（9,10-naphthalenediyl）bis-benzoic acid（H₂NDBA）,以构筑特定的骨架结构.利用调节剂法,通过八水合氯氧化锆与有机配体H₂NDBA的溶剂热反应,合成了具有预期fcu拓扑结构的[Zr₆（μ₃-O）₄（μ₃-OH）₄（NDBA）₆]·7DMF·4H₂O（JLU-MOF100）.该MOF材料具有高孔隙率和良好的水稳定性.得益于有机配体中的萘基团, JLU-MOF100具有优异的荧光性质,基于荧光猝灭效应,在水中对硝基芳烃爆炸物展现出良好的荧光检测性能.更多还原

【Abstract】 Guided by molecular building block（MBB） approach,a naphthalene-based linear organic ligand 4,4′（-9,10-naphthalenediyl） bis-benzoic acid（H₂ NDBA）is designed and synthesized to build the oriented framework.By using the modulator method,the solvothermal reaction of ZrOCl₂·8H₂O and H₂NDBA ligand yields the[Zr（₆μ₃-O）·4（μ₃-OH）₄（NDBA）₆]·7 DMF·4H₂O（JLU-MOF100）with anticipated fcu topology. JLU-MOF100 displays high porosity and good water stability. Benefiting from the naphthalene group in the ligand,JLU-MOF100 exhibits significant fluorescent properties. It shows good performance in the detection of different nitroaromatic explosives in water by quenching effect.更多还原