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双重交联壳聚糖海绵的制备及其在油水分离中的应用研究

Fabrication of dual Crosslinked Chitosan Sponges and its Application for Oil/Water Separation

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【作者】 邱洪茂; 侯婷婷; 张彤;

【Author】 Qiu Hongmao;Hou Tingting;Zhang Tong;School of Chemistry and Environment Science, Guangdong Ocean University;

【通讯作者】 张彤;

【机构】 广东海洋大学化学与环境学院;

【摘要】 为探索壳聚糖在含油污水处理中的应用前景,本文采用物理和化学交联法,制备了柠檬汁和香茅醛双交联壳聚糖海绵(DCS-C)。研究发现,DCS-C具有良好的弹性,经十次压缩后,其恢复率可达99.2%。此外,DCS-C的接触角为121.1±1.4°,具有良好的疏水性能。实验条件下,DCS-C可有效除去多种有机溶剂(或油),经15次吸附-脱吸附处理后,其吸附容量仍大于12 g/g。油水分离实验表明,DCS-C不仅可选择性分离油水混合物,还可高效分离水包油乳液中的二氯甲烷(DCM)。以上研究表明,DCS-C可应用于实际工业中含油污水的纯化。

【Abstract】 To explore the application prospects of chitosan in oil-containing wastewater, dual crosslinked chitosan sponge(DCS-C) was fabricated using physical and chemical crosslinking method, via lemon juice and citronellal. It was found that DCS-C possesses excellent elasticity and compressibility, which can remain 99.2 % of the original height after 10 squeezes. Furthermore, DCS-C exhibits good hydrophobicity with a contact angle of 121.1±1.4°. Under the experimental conditions, DCS-C can remove organic solvents(or oils) effectively after 15 cycles of adsorption-desorption, with an adsorption capacity higher than 12g/g. Oil-water separation experiments show that DCS-C cannot only selectively separate oil/water mixtures, but also effectively separate dichloromethane(DCM) in oil-in-water emulsion. In conclusions, DCS-C can be used to purify oil-containing wastewater in practical industries.

【关键词】 壳聚糖; 海绵; 香茅醛; 油水分离;
【Key words】 chitosan; sponge; citronellal; oil/water separation;
【基金】 广东省自然科学基金面上项目(2020A1515011011);广东省大学生创新创业项目(CXXL2019102)
  • 【文献出处】 广东化工 ,Guangdong Chemical Industry , 编辑部邮箱 ,2022年13期
  • 【分类号】X703;TB34
  • 【下载频次】126
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