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基于聚离子液体的常压阴离子可染聚丙烯纤维制备及其性能

Preparation and properties of normal pressure-anionic dyeable polypropylene fiber based on polyionic liquid

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【作者】 梁姣姣汪菁晶夏于旻朱新远闫冰孙利明王燕萍何勇王依民

【Author】 LIANG Jiaojiao;WANG Jingjing;XIA Yumin;ZHU Xinyuan;YAN Bing;SUN Liming;WANG Yanping;HE Yong;WANG Yimin;Engineering Research Center of Technical Textile, Ministry of Education, Donghua University;College of Materials Science and Engineering, Donghua University;School of Chemistry and Chemical Engineering, Shanghai Jiaotong University;Zhejiang Hongji Petrochemical Co., Ltd.;Innovation Center for Textile Science and Technology, Donghua University;

【通讯作者】 夏于旻;

【机构】 东华大学产业用纺织品教育部工程研究中心东华大学材料科学与工程学院上海交通大学化学化工学院浙江鸿基石化股份有限公司东华大学纺织科技创新中心

【摘要】 为改善聚丙烯纤维的染色性能,使其达到阴离子染料可染的效果,设计合成了一种主链是阳离子型的聚离子液体,对其与聚丙烯共混体系的相容性进行研究;将共混体系通过熔融纺丝得到阴离子可染聚丙烯纤维,借助纱线强伸度仪研究了纤维的力学性能,并通过染色实验对纤维的染色性能进行分析。结果表明:聚丙烯与聚离子液体共混体系具有良好相容性,聚离子液体的加入使聚丙烯的结晶度和取向度降低,从而使得其改性聚丙烯纤维更有利于与染料结合;改性聚丙烯纤维的上染率达到17.0%,染色深度值达到5.450 3,且改性纤维的断裂强度为4.4 cN/dtex,符合纺织加工的要求。

【Abstract】 In order to prepare anionic dyeable polypropylene fiber, a type of cationic polyionic liquid was designed and synthesized, and its compatibility with the polypropylene blend system was studied. The blended system was spun into yarns by melt spinning method, and its mechanical properties and dyeing properties were investigated. Results show that the blending system of polypropylene and polyionic liquid has good compatibility. The addition of polyionic liquid reduces the degree of crystallinity and orientation of polypropylene, which makes the modified polypropylene fiber more favorable to combine with the dye. Dyeing experiment on the modified fiber showed that the dyeing rate and the dyeing depth of the fiber reaches 17.0% and 5.450 3 respectively. The breaking strength of the modified fiber is 4.4 cN/dtex, which meets the requirements for textile processing.

【基金】 中央高校基本科研业务费专项资金项目(2232021G-06)
  • 【文献出处】 纺织学报 ,Journal of Textile Research , 编辑部邮箱 ,2022年07期
  • 【分类号】TQ342.62
  • 【下载频次】73
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