【摘要】 以正辛酸-氯化锌型低共熔溶剂（OA-ZnCl₂）为添加组分、硅胶（SG）为载体，经溶胶-凝胶过程合成OA-ZnCl₂/SG负载型催化剂。采用红外光谱、X射线衍射、N₂-吸附脱附和扫描电镜等技术对催化剂的结构进行分析。以OA-ZnCl2/SG为吸附剂和催化剂、双氧水为氧化剂，研究其氧化脱硫性能。考察了低共熔溶剂的负载量、反应温度、n（H₂O₂）/n（S）、催化剂质量和不同硫化物对脱硫效果的影响。结果表明，在最佳条件下催化剂的脱硫率达到95.6%，经过5次循环后脱硫率降为89.7%。更多还原

【Abstract】 OA-ZnCl₂/SG supported catalyst was synthesized by sol-gel process using octanoic acid-zinc chloride deep eutectic solvents（OA-ZnCl₂DESs） as additive. The structure of the catalyst was analyzed by infrared spectroscopy, X-ray diffraction,N₂ adsorption-desorption and scanning electron microscopy. The performance of oxidative desulfurization was studied by using OA-ZnCl₂/SG as adsorbent and catalyst, and hydrogen peroxide as oxidant. The loading dose of DESs, reaction temperature,n（H₂O₂）/n（S） ratio, the amount of catalyst and the effect of different sulfides on desulfurization rate were investigated. The results show that the desulfurization rate of the catalyst reaches 95.6% under the optimal conditions, and after 5 cycles, the desulfurization rate drops to 89.7%.更多还原