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Ru/NiFe LDH/Ni Foam催化剂的制备及全解水性能研究

Preparation and Complete Water Splitting Performances of Ru/NiFe LDH/Ni Foam Catalyst

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【作者】 吴敏赵红刘宏文刘德宠

【Author】 WU Min;ZHAO Hong;LIU Hongwen;LIU Dechong;School of Environmental Science and Engineering, Dalian Jiaotong University;Dalian Municipal Environmental Monitoring Center;GEM (Wuxi) Energy Material Co., Ltd;

【机构】 大连交通大学环境与化学工程学院大连市环境检测中心格林美(无锡)能源材料有限公司

【摘要】 通过水热法和一步还原法制备自支撑三维立体结构的Ru/NiFe LDH/Ni Foam双功能催化剂.Ru/NiFe LDH/Ni Foam催化剂在1M KOH的介质中,析氧反应(OER)在电流密度为10 mA·cm-2的过电位为228 mV,析氢反应(HER)在电流密度为10 mA·cm-2的过电位为66 mV,在全解水两电极体系中在10 mA·cm-2的电流密度下电位为1.70 V.

【Abstract】 A self-supporting three-dimensional structure Ru/NiFe LDH/Ni Foam bifunctional catalyst was prepared by hydrothermal and one-step reduction methods. Because Ru/NiFe LDH/Ni foam has a three-dimensional structure, this array-type three-dimensional structure is conducive to gas desorption, and a large specific surface area provides more active sites. These characteristics are conducive to improving the catalytic performance of the catalyst. In 1 M KOH medium, the overpotential of the oxygen evolution reaction(OER) of the Ru/NiFe LDH/Ni foam catalyst is 228 mV at a current density of 10 mA·cm-2, and the overpotential of the hydrogen evolution reaction(HER) is 66 mV at a current density of 10 mA·cm-2. The catalyst has a potential of 1.70 V at a current density of 10 mA·cm-2 in a two-electrode system for complete water splitting.

【基金】 国家自然科学基金资助项目(21776027)
  • 【文献出处】 大连交通大学学报 ,Journal of Dalian Jiaotong University , 编辑部邮箱 ,2022年02期
  • 【分类号】TQ116.2;O643.36
  • 【下载频次】72
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