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二氧化硅气凝胶/三元乙丙橡胶复合隔热材料的制备与性能研究

Study on preparation and performance of silica aerogel/EPDM composite thermal insulation material

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【作者】 王振豪陈勃高飞汪书苹李向梅刘晶冰

【Author】 WANG Zhen-hao;CHEN Bo;GAO Fei;WANG Shu-ping;LI Xiang-mei;LIU Jing-bing;Department of Materials and Manufacturing, Beijing University of Technology;Beijing Institute of Technology, School of Materials Science and Engineering,National Engineering Research Center of Flame Retardant Materials;China Electric Power Research Institute State Key Laboratory of Operation and Control of Renewable Energy & Storage Systems;Anhui Province Key Laboratory for Electric Fire and Safety Protection of State Grid Anhui Electric Power Research Institute;

【通讯作者】 刘晶冰;

【机构】 北京工业大学材料与制造学部北京理工大学材料学院国家阻燃材料工程技术研究中心中国电力科学研究院有限公司新能源与储能运行控制国家重点实验室国网安徽省电力有限公司电力科学研究院电力火灾与安全防护安徽省重点实验室

【摘要】 本文合成制备了SA/EPDM隔热复合材料,研究了不同SA/EPDM含量比例以及添加阻燃剂后的复合材料的隔热性能、热稳定性能以及力学性能。当火源温度为300℃和500℃时,SA含量为70%的复合材料背面温度维持在130℃和250℃,导热系数为0.2253 W/m·K。热失重分析结果表明,SA含量的升高虽然没有延缓材料的高温降解速率,但是SA含量的加入减小了复合材料玻璃化转变放热量,在促进材料成炭中起到了积极作用,残碳量最高为50.67%,并且复合材料力学性能表现优秀,拉伸强度可达22.45 MPa,断裂伸长率可达661.90%。

【Abstract】 In this paper, SA/EPDM thermal insulation composite materials were synthesized and prepared, and the thermal insulation performance, thermal stability performance and mechanical properties of the composite materials with different SA/EPDM content ratios and the addition of flame retardants were studied. When the fire source temperature is 300 ℃ and 500 ℃, the back surface temperature of the composite material with 70% SA content is maintained at 130 ℃ and 250 ℃, and the thermal conductivity is 0.2253 W/m·K. The thermal weight loss analysis shows that although the increase of SA content does not delay the high-temperature degradation rate of the material, the addition of SA content reduces the heat of glass transition of the composite material, and plays a positive role in promoting the carbon formation of the material. The highest is 50.67%, and the mechanical properties of the composite material are excellent, the tensile strength can reach 22.45 MPa, and the elongation at break can reach 661.90%.

【基金】 国家电网有限公司总部科技项目“锂离子电池储能系统主动协同安全防护技术开发与应用研究”(DG71-20-025)
  • 【文献出处】 复合材料科学与工程 ,Composites Science and Engineering , 编辑部邮箱 ,2022年01期
  • 【分类号】TB332
  • 【被引频次】1
  • 【下载频次】562
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