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NaSal/KCl诱导阳离子表面活性剂形成胶束的微观机理研究

Study on the micro-mechanism of NaSal/KCl induce cationic surfactants to form micelles

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【作者】 李培枝王江涛杨晓武李志刚

【Author】 LI Pei-zhi;WANG Jiang-tao;YANG Xiao-wu;LI Zhi-gang;Key Laboratory of Auxiliary Chemiscry & Technology for Chemical Industry, Ministry of Education, Shaanxi University of Science & Technology;

【机构】 陕西科技大学教育部轻化工助剂化学与技术重点试验室

【摘要】 为了研究丙撑基双(十八烷基二甲基氯化铵)(简写18-3-18)、氯化钾和水杨酸钠复配形成胶束体系的机理,并且找到其构成的粘弹性表面活性剂(VES)压裂液体系的最佳配比,本文采用扫描电子显微镜(SEM)来观察不同组分与粘弹性表面活性剂混合所具有的微观结构,采用粘度计测量其粘度以找到最佳配比,并且加入聚氧乙烯以期望进一步提高其粘弹性.结果表明:当18-3-18的浓度固定为2 wt%、调节氯化钾含量为7 wt%、水杨酸钠含量为0.6 wt%时,形成的VES压裂液粘弹性最佳,并且在加入0.1 wt%的聚氧乙烯之后,其体系粘度均有大幅度增加,且在高剪切速率下效果更好.

【Abstract】 In order to study the mechanism of the formation of micelle system by the combination of propylene bis(octadecyl dimethyl ammonium chloride)(abbreviated as 18-3-18),potassium chloride and sodium salicy-late,and to find the viscosity The best ratio of elastic surfactant(VES) fracturing fluid system.In this paper,scanning electron microscope(SEM) is used to observe the microstructure of different components mixed with viscoelastic surfactant,and the viscosity is measured with a viscometer.Find the best ratio,and add polyoxy-ethylene to hope to further improve its viscoelasticity.The results show that when the concentration of 18-3-18 is fixed at 2 wt%,the potassium chloride content is adjusted to 7 wt%,the sodium salicylate content is at 0.6 wt%,the formed VES fracturing fluid has the best viscoelasticity,and after adding 0.1 wt% polyoxyethylene,the viscosity of the system has increased significantly,and the effect is better at high shear rate.

【基金】 国家自然科学基金项目(51603117);陕西省高校科协青年人才托举计划项目(20190604);陕西省教育厅重点实验室科研计划项目(18JS013)
  • 【文献出处】 陕西科技大学学报 ,Journal of Shaanxi University of Science & Technology , 编辑部邮箱 ,2021年01期
  • 【分类号】TE357.12
  • 【被引频次】1
  • 【下载频次】231
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