【摘要】 合成了3个不同结构的吡啶-2-甲醛缩对氯苯氧乙酰腙（HL）与镉的配合物。通过X射线单晶衍射、红外光谱、紫外光谱、荧光光谱以及热重等分析,对其进行晶体结构和性质的研究。单晶衍射结构解析表明:配合物1属单斜晶系,C2/c空间群,是一个通过氯离子桥联的二聚体,分子式为[Cd（HL）Cl₂]₂;配合物2属单斜晶系,P2₁/c空间群,是一个含2个有机配体、蝴蝶状的单核分子,其分子式为[Cd（HL）₂Br₂];配合物3属三斜晶系,■空间群,配合物中只含有一个有机配体,其分子式为[Cd（HL）I₂]。固体荧光分析表明:配体和配合物均有很强的荧光性,且发绿光。更多还原

【Abstract】 Three complexes,[Cd（HL）Cl₂]₂（1）,[Cd（HL）₂Br₂]（2） and[Cd（HL）I₂]（3）（HL=2-（4-chlorophenoxy）-N′-（pyridin-2-ylmethylene）acetohydrazide）,were synthesized using a common solution method.The crystal structure and properties were studied by X-ray single crystal diffraction,infrared spectrum,ultraviolet spectrum,fluorescence spectrum and thermogravimetric analysis.The analysis of single crystal diffraction structure shows that complex1belongs to monoclinic system,C2/c space group,and is a dimer bridged by chlorine ions.Complex 2 belongs to monoclinic system,P2₁/c space group.It is a butterfly shaped mononuclear molecule containing two organic ligands.The central Cd²⁺ions of complexes1and2are in a distorted octahedral position.Complex 3 belongs to triclinic system,■ space group,in which there is only one organic ligand.The coordination polyhedron of Cd²⁺ion of complex 3 is distorted trigonal bipyramid.Solid fluorescence analysis showed that both ligand and complexes had strong fluo-rescence and emitted green light.CCDC:2011521,1;2011522,2;2011523,3.更多还原