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聚吡咯/石墨相氮化碳光催化材料的制备及其铀降解性能研究

Synthesis of PPy/g-C3N4 photocatalytic materials and its degradation properties towards uranium

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【作者】 俞坤葛玉杰谢水波刘迎九刘金香

【Author】 YU Kun;GE Yu-jie;XIE Shui-bo;LIU Ying-jiu;LIU Jin-xiang;School of Civil Engineering,University of South China;Hunan Provincial Key Laboratory of Pollution Control and Resources Technology,University of South China;

【通讯作者】 刘金香;

【机构】 南华大学土木工程学院南华大学污染控制与资源化技术湖南省重点实验室

【摘要】 为了提高g-C3N4的光催化性能,通过原位聚合法制备了PPy/g-C3N4复合材料。通过SEM、XRD、BET和FTIR等表征手段研究PPy/g-C3N4的微观形貌、化学组成以及光催化降解铀的性能。结果表明,PPy抑制了g-C3N4晶粒的生长,提高了g-C3N4的比表面积。在降解时间60 min,pH=5,U(VI)初始浓度5 mg/L,光催化剂投加量200 mg/L的条件下,g-C3N4和PPy/g-C3N4复合材料对U(VI)的降解率分别为83.11%和96.20%。重复使用3次后,PPy/g-C3N4对U(VI)的降解率仍达92.4%。

【Abstract】 In order to improve the photocatalytic performance of g-C3N4,PPy/g-C3N4 composites were prepared by in-situ polymerization.SEM,XRD,BET and FTIR were used to study the PPy/g-C3N4 micromorphology,chemical composition and photocatalytic degradation of uranium.The results show that PPy inhibits the growth of g-C3N4 grains and increases the specific surface area of g-C3N4.When the degradation time was 60 min,pH=5,the initial concentration of U(VI) was 5 mg/L,and the amount of photocatalyst was 200 mg/L.g-C3N4 and PPy/g-C3N4 composites on the degradation rates of U(VI) were 83.11% and 96.20%,respectively.After repeated use 3 times,the degradation rate of U(VI) by PPy/g-C3N4 still reached 92.4%.

【基金】 国家自然科学基金(11475080);南华大学博士科研启动基金项目(2016XQD06);湖南省研究生创新项目(CX20190742)
  • 【文献出处】 应用化工 ,Applied Chemical Industry , 编辑部邮箱 ,2021年01期
  • 【分类号】O643.36;O644.1;X771
  • 【被引频次】1
  • 【下载频次】323
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