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活性炭对于二氯乙酸和二溴乙酸吸附机理研究
Adsorption Mechanism of Dichloroacetic Acid and Dibromoacetic Acid on Activated Carbon
【摘要】 通过吸附动力学实验和吸附等温实验,探究了活性炭吸附二氯乙酸(DCAA)和二溴乙酸(DBAA)反应的动力学关系及吸附类型。实验结果表明,活性炭吸附DCAA和DBAA反应更加符合Langmuir等温吸附模型,吸附表现为单分子层吸附;动力学上更符合准二级动力学方程,表现为反应速率主要受内膜扩散控制。
【Abstract】 The kinetic relationship and adsorption type of dichloroacetic acid(DCAA) and dibromoacetic acid(DBAA) adsorbed on activated carbon were studied by adsorption kinetics experiment and adsorption isotherm experiment. The experimental results show that the adsorption of DCAA and DBAA on activated carbon is more consistent with Langmuir isotherm model, and the adsorption is monolayer adsorption. The kinetic experment is more consistent with the pseudo-second order kinetic model and the reaction rate is mainly controlled by internal diffusion.
【关键词】 活性炭;
二氯乙酸;
二溴乙酸;
吸附;
【Key words】 Activated carbon; Dichloroacetic acid; Dibromoacetic acid; Adsorption;
【Key words】 Activated carbon; Dichloroacetic acid; Dibromoacetic acid; Adsorption;
- 【文献出处】 辽宁化工 ,Liaoning Chemical Industry , 编辑部邮箱 ,2021年04期
- 【分类号】TU991.2
- 【被引频次】1
- 【下载频次】218