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两性磁化炭添加比例对河流沿岸土吸附Cu2+的影响
Effect of Amphoteric-Magnetized Biochar Addition Ratio on Cu2+ Adsorption in Riverbank Soils
【摘要】 将两性(十二烷基二甲基甜菜碱)修饰磁化炭分别以质量分数0、1%和2%加入嘉陵江流域(川渝段)内苍溪(CX)、南部(NB)、嘉陵(JL)和合川(HC)沿岸土中,考察各混合土样对Cu2+的等温吸附和热力学特征。结果表明:混合土样对Cu2+的最大吸附量为58.36 mmol/kg~366.85 mmol/kg,添加等量两性磁化炭时各混合土样对Cu2+吸附量表现为JL>NB>CX>HC的趋势,且添加比越高吸附能力越强。各混合土样对Cu2+的吸附为自发、吸热和熵增的反应过程,对Cu2+的吸附量与温度和pH值均呈正相关关系。当离子强度为0.1 mol/L时,各混合土样(除HC外)对Cu2+的吸附量最大。
【Abstract】 Amphoteric(dodecyl dimethyl betaine) modified magnetized biochar was added into the riverbank soils in Cangxi(CX), Nanbu(NB), Jialing(JL) and Hechuan(HC)along the Jialing River by 0, 1% and 2% mass ratio. The adsorption isotherms and thermodynamic characteristics of Cu2+in each mixed soil sample were studied. The results indicated that the maximum Cu2+adsorption amount in mixed soil samples were between 58.36 mmol/kg and 366.85 mmol/kg. Cu2+ adsorption had a trend of JL> NB>CX>HC when adding equivalent amphoteric magnetized biochar to each mixed soil sample. The adsorption capacity increased as the addition ratio increased. The adsorption of Cu2+ in each mixed soil sample was a spontaneous, endothermic and entropy increase reaction process. Cu2+ adsorption was positively correlated with temperature and pH value. When ion strength was 0.1 mol/L, the adsorption amount of Cu2+ in each mixed sample(except HC) was the largest.
【Key words】 Cu2+; Amphoteric magnetized biochar; Adsorption amount; Jialing River; Riverbank soil;
- 【文献出处】 环境监测管理与技术 ,The Administration and Technique of Environmental Monitoring , 编辑部邮箱 ,2021年01期
- 【分类号】X53
- 【下载频次】78