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吉布斯-亥姆霍兹方程在无机化学中的应用
Application of Gibbs-Helmholtz Equation in Inorganic Chemistry
【摘要】 介绍了吉布斯-亥姆霍兹方程以及吉布斯-亥姆霍兹方程应用的一般方法。讨论了吉布斯-亥姆霍兹方程在无机化学中的各种应用:反应的热力学转变温度的定量计算,物质的溶解性定性和定量解释,单质的化学活泼性以及无机酸的酸性强弱的定量解释。通过归纳,应用吉布斯-亥姆霍兹方程,可以定性和定量地解释和讨论物质的某些物理性质和化学性质。
【Abstract】 Gibbs-Helmholtz equation and the general method of its applicationwere introduced. Various applications of Gibbs-Helmholtz equation in inorganic chemistry were discussed, including quantitative calculation of thermodynamic transition temperature of reaction, qualitative and quantitative interpretation of matter solubility, quantitative explanation of chemical activity of single substance and acidity of inorganic acid. Through induction, some physical and chemical properties of matter can be explained and discussed qualitatively and quantitatively by using Gibbs Helmholtz equation.
【Key words】 Gibbs-Helmholtz equation; inorganic chemistry; thermodynamic transition temperature; solubility; chemical activity; acidity;
- 【文献出处】 广州化工 ,Guangzhou Chemical Industry , 编辑部邮箱 ,2021年14期
- 【分类号】G642;O61-4
- 【下载频次】194