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氧化松木生物炭高效去除水中Pb及定量吸附机理
Efficient removal and quantitative adsorption mechanisms of Pb from water by oxidized pine biochars
【摘要】 用H2O2、KMnO4(Mn)和Mn(CH3COO)2·4H2O(MnC)改性松木生物炭(PW),通过吸附实验和表征探究其对Pb的去除能力和去除机理,并定量分析各种吸附机制的贡献率。PW-H2O2、PW-Mn、PW-MnC对溶液中Pb的吸附量分别是原始生物炭的6、8.5、7.9倍。两种锰改性生物炭比表面积显著提高,其表面形成了MnO2。阳离子交换对吸附的贡献率占PW-Mn、PW-MnC吸附Pb的74.6%、87.5%。表明BC-MnC是一种去除工业废水中重金属Pb的综合性能优异的材料。
【Abstract】 Biochar was prepared from pine wood(PW) and modified by H2 O2,KMnO4 a nd Mn(CH3 COO)2·4 H2 O.The removal capacity and mechanism of Pb was explored through adsorption experiments and characterization,and various adsorption mechanisms were quantitatively analyzed to reveal the contribution rate of each mechanism. The adsorption capacity of Pb in the water of PW-H2O2,PW-Mn,PW-MnC was 6,8.5 and 7.9 times that of the original biochar. The specific surface area of two kinds of manganese-modified biochar increased obviously and on the surface of which MnO2 were formed. And the contribution rate of cation exchange to adsorption accounted for 74.6% and 87.5%of Pb adsorption. The results showed that PW-MnC was a kind of material with excellent comprehensive performance in removing heavy metal Pb from industrial wastewater.
- 【文献出处】 工业水处理 ,Industrial Water Treatment , 编辑部邮箱 ,2021年07期
- 【分类号】X703
- 【被引频次】3
- 【下载频次】461