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窄分布脂肪醇醚硫酸盐制备条件对产品中二噁烷含量的影响
Effects of preparation conditions on the content of 1,4-dioxane in the product of narrow-distribution sodium fatty alcohol ether sulfate
【摘要】 在实验室三氧化硫降膜式硫酸化装置上,分别以n(SO3)∶n(窄分布脂肪醇醚(AEO))、硫酸化温度、SO3体积分数、脂肪醇醚硫酸酯放置时间和中和温度为单因素变量,研究了窄分布脂肪醇醚硫酸盐(窄分布AES)产品中二噁烷的含量变化。结果表明:随着体系中n(SO3)∶n(窄分布AEO)的增加、硫酸化温度的升高、SO3体积分数的升高、脂肪醇醚硫酸酯放置时间的延长和中和温度的升高,窄分布AES中二噁烷的含量增加。
【Abstract】 The content of 1,4-dioxane in narrow-distribution sodium fatty alcohol ether sulfate(narrowdistribution AES) was studied by using n(SO3)∶n(narrow-distribution fatty alcohol ether),sulfation temperature,volume fraction of SO3,storage time and neutralization temperature as single-factor variables on a laboratory device of sulfur trioxide falling film sulfation.The results showed that,the content of 1,4-dioxane in narrow-distribution AES would increase with the increase of excess SO3,sulfation temperature,volume fraction of SO3,storage time of narrow-distribution fatty alcohol ether,and neutralization temperature.
【Key words】 sulfur trioxide; narrow-distribution sodium fatty alcohol ether sulfate; 1,4-dioxane;
- 【文献出处】 日用化学工业 ,China Surfactant Detergent & Cosmetics , 编辑部邮箱 ,2021年01期
- 【分类号】TQ423.11
- 【被引频次】2
- 【下载频次】68