【摘要】 采用磁控溅射法在不同基底温度下制备Co-TiO₂纳米复合薄膜。所合成的纳米复合薄膜由TiO₂非晶基体和分散其中的Co颗粒组成,呈铁磁和超顺磁共存的特性。随着基底温度从室温升高到400°C,Co颗粒尺寸逐渐增大,氧化程度明显降低。因此,在Co含量相同的情况下,随着基底温度的升高（从室温升高至400°C）,饱和磁化强度从0.13增加到0.43 T。在高基底温度下,一部分Co颗粒聚集形成导电路径,导致电阻率从1600快速下降至76μΩ·m。即使在电阻率低至76μΩ·m的情况下,依然能获得Co-TiO₂的磁电阻性能。结果表明,纳米复合薄膜在室温下具有低Co氧化、高磁化强度和磁阻特性。更多还原

【Abstract】 Co-TiO₂ nanocomposite films were prepared via magnetron sputtering at various substrate temperatures. The films comprise Co particles dispersed in an amorphous TiO₂ matrix and exhibit coexisting ferromagnetic and superparamagnetic properties. When the substrate temperature increases from room temperature to 400 °C, Co particles gradually grow, and the degree of Co oxidation significantly decreases. Consequently, the saturation magnetization increases from 0.13 to 0.43 T at the same Co content by increasing the substrate temperature from room temperature to 400 °C. At a high substrate temperature, conductive pathways form among some of the clustered Co particles. Thus, resistivity rapidly declines from 1600 to 76 μΩ·m. The magnetoresistive characteristic of Co-TiO₂ films is achieved even at resistivity of as low as 76 μΩ·m. These results reveal that the obtained nanocomposite films have low Co oxidation, high magnetization and magnetoresistance at room temperature.更多还原