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氮离子注入诱导TiO2涂层在可见光下的抗菌能力(英文)

Induced antibacterial capability of TiO2 coatings in visible light via nitrogen ion implantation

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【作者】 郑立钱仕刘宣勇

【Author】 Li ZHENG;Shi QIAN;Xuan-yong LIU;State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences;College of Materials Science and Opto-Electronics Engineering, University of Chinese Academy of Sciences;

【通讯作者】 钱仕;刘宣勇;

【机构】 中国科学院上海硅酸盐研究所高性能陶瓷和超微结构国家重点实验室中国科学院大学材料科学与光电技术学院

【摘要】 为了提高钛组件的抗菌能力,通过微弧氧化(MAO)处理和进一步的氮等离子体浸没离子注入(N-PIII)处理,在钛表面制备抗菌涂层。XPS光谱测试结果表明,采用氮离子注入N-PIII法将氮掺入TiO2涂层,随着注入时间的增加,TiO2涂层表面氮含量增加。掺氮样品在可见光区域的吸光度显著增加,并且氮注入样品的光吸收峰边缘与微弧氧化样品的光吸收峰相比向红外光区移动。将大肠杆菌和金黄色葡萄球菌接种在样品表面,以评估样品的抗菌能力。细菌实验结果表明,掺氮态TiO2在可见光下可以有效降低细菌活力。由实验结果可见,微弧氧化和氮离子注入复合工艺制备的抗菌TiO2涂层在医学和海洋领域具有很大潜力。

【Abstract】 In order to enhance the antibacterial ability of titanium components, an antibacterial coating was fabricated on Ti surface by micro-arc oxidation(MAO) and further nitrogen plasma immersion ion implantation(N-PIII). The XPS spectra demonstrated that nitrogen was incorporated into TiO2 coatings by N-PIII and the nitrogen content on the surface of TiO2 coatings increased as the N-PIII time increased. Nitrogen-incorporated samples exhibited remarkably increased absorbance in the visible region and the light absorption edge of nitrogen-incorporated samples showed a redshift compared to MAO samples. Escherichia coli and Staphylococcus aureus were seeded on the samples to assess their antibacterial ability. The bacterial experiment demonstrated that nitrogen-incorporated TiO2 could effectively reduce the bacterial viability in visible light. Thus, the antibacterial TiO2 coatings fabricated by MAO and further N-PIII might have large potential in the medical and marine fields.

【基金】 Projects(51831011,31670980)supported by the National Natural Science Foundation of China;Project(51525207)supported by the National Natural Science Foundation for Distinguished Young Scholars of China;Projects(18YF1426900,18410760600)supported by the Science and Technology Commission of Shanghai Municipality,China
  • 【文献出处】 Transactions of Nonferrous Metals Society of China ,中国有色金属学报(英文版) , 编辑部邮箱 ,2020年01期
  • 【分类号】R318.08;TG174.4
  • 【被引频次】3
  • 【下载频次】106
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