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德州市典型溶剂使用行业VOCs排放特征及末端治理技术研究

Study on Emission Characteristics and End-Control Measurements for VOCs from Typical Solvent-Usage Industries in Dezhou City

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【作者】 雒瑞张巍张培勇李登黄成刘杰修光利

【Author】 Luo Rui;Zhang Wei;Zhang Peiyong;Li Deng;Huang Cheng;Liu Jie;Xiu Guangli;Shanghai Key Laboratory of Environmental Standards and Risk Management of Chemical Pollutants,East China University of Science and Technology;National Environmental Protection Chemical Process Environmental Risk Assessment and Control Key Laboratory;Shanghai Institute of Pollution Control and Ecological Safety;Shandong Province Dezhou City Ecological Environment Bureau;Shanghai Academy of Environmental Sciences;China National Coatings Industry Association;

【通讯作者】 张巍;

【机构】 上海市环境保护化学污染物环境标准与风险管理重点实验室华东理工大学国家环境保护化工过程环境风险评价与控制重点实验室上海污染控制与生态安全研究院山东省德州市生态环境局上海市环境科学研究院中国涂料工业协会

【摘要】 对4个典型溶剂使用行业(玻璃纤维塑料制品制造业、家具制造业、包装印刷业和汽车制造业)的128家企业进行了调研,并选择其中20家企业进行了采样,分析排放口VOCs物种和非甲烷总烃(NMHC)浓度。结果表明:芳香烃和含氧VOCs为4个行业共同的主要排放物种;同时光解(催化)技术在末端治理技术中应用最为普遍,占比67.0%以上,但是处理效率较低(33.2%)。通过估算企业有组织VOCs年排放量以及总VOCs年排放量,发现相关企业均可能存在无组织排放量较大的问题。最后通过对比发现德州市各行业排放特征同已有研究中其他国内省市的对应行业基本一致,但在德州市家具制造行业和汽车制造行业的特征污染物中分别检测到了异丙醇和苯,需引起一定重视。

【Abstract】 In order to understand the emission characteristics of volatile organic compounds(VOCs)from typical solvent usage industries in Dezhou City,Shandong Province,four typical solvent usage industries including glass fiber plastic products manufacturing,furniture manufacturing,packaging and printing,and automobile manufacturing were surveyed. Among which,128 companies were investigated on site and 20 companies were selected to collect gas samples and analyze VOCs and non-methane hydrocarbon(NMHC)concentrations. By analyzing the VOCs species in the four typical industries,we found that aromatic hydrocarbons and oxygenated VOCs dominated the emission species,and the photolysis(catalysis) technology was the most common VOCs end treatment technique in 4 typical industries in Dezhou City,which accounted for more than 67.0%,but their removal efficiency for NMHC was low(33. 2%). By estimating the annual emissions of organized VOCs and the total annual emissions of VOCs,it was found that the unorganized emissions dominated in related enterprises. Finally,the emission characteristics of VOCs species from the furniture manufacturing,automobile manufacturing and packaging printing industries in Dezhou City was relatively consistent with those from previous publications measured in other provinces and cities,but isopropanol and benzene was detected from furniture manufacturing,and the automotive industry respectively in Dezhou City,which should be further concerned for VOCs control.

【基金】 大气重污染成因与治理攻关项目(DOGG-05-18);上海市科委项目(18DZ206702)
  • 【文献出处】 涂料工业 ,Paint & Coatings Industry , 编辑部邮箱 ,2020年09期
  • 【分类号】X701
  • 【被引频次】4
  • 【下载频次】259
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