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微波法制备银镁共掺氧化锌复合光催化剂及其光催化性能研究

MICROWAVE-ASSISTED SYNTHESIS OF SILVER-MAGNESIUM CO-DOPED ZINC OXIDE AND ITS PHOTOCATALYTIC PERFORMANCE

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【作者】 孙博吴限张金生李丽华

【Author】 Sun Bo;Wu Xian;Zhang Jinsheng;Li Lihua;College of Chemistry,Chemical Engineering and Environmental Engineering,Liaoning Shihua University;

【通讯作者】 李丽华;

【机构】 辽宁石油化工大学化学化工与环境学部

【摘要】 采用环形聚焦单模微波辅助法(简称微波法)快速合成银镁共掺氧化锌复合光催化剂(简称复合光催化剂),并运用X射线衍射、扫描电子显微镜对其结构和形貌进行表征。将此复合光催化剂应用于光催化降解罗丹明B和含油污水,研究其光催化性能并探究光催化降解机理。结果表明:微波法合成的复合光催化剂具有良好的光催化性能,对含油污水的降解率优于商用二氧化钛;复合光催化剂重复使用4次后罗丹明B的降解率仍维持在92%以上,化学稳定性良好。

【Abstract】 A ring-focusing single-mode microwave synthesis method was used to rapidly synthesize a composite photocatalyst of silver-magnesium co-doped ZnO. XRD and SEM were used to characterize the structure and morphology of the synthesized photocatalyst. The photocatalytic degradation of Rhodamine B and oily wastewater by the photocatalyst was investigated. The performance and the mechanism of the reactions were explored. The results showed that the composite photocatalyst synthesized by microwave method had a good photocatalytic performance,and the degradation rate for oily wastewater was better than that of commercial titanium dioxide. After four cycles,the degradation rate of Rhodamine B was still above 92%,indicating that its chemical stability was good.

【关键词】 微波法氧化锌光催化剂含油污水
【Key words】 microwave methodzinc oxidephotocatalystoily wastewater
  • 【文献出处】 石油炼制与化工 ,Petroleum Processing and Petrochemicals , 编辑部邮箱 ,2020年06期
  • 【分类号】X703;O643.36;O644.1
  • 【被引频次】2
  • 【下载频次】128
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