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典型挥发性有机物在疏水Y分子筛上的吸/脱附研究

Study on Adsorption/Desorption of Typical Volatile Organic Compounds on Hydrophobic Y Zeolites

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【作者】 任超高君安潘利鹏张傑朱吉钦

【Author】 Ren Chao;Gao Jun′an;Pan Lipeng;Zhang Jie;Zhu Jiqin;Shanxi Lu′an Coal Based Clean Energy Co., Ltd.;State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology;

【机构】 山西潞安煤基清洁能源有限责任公司北京化工大学化工资源有效利用国家重点实验室

【摘要】 针对高湿度条件下常规Y分子筛吸附VOCs性能不佳的问题,以常规Y分子筛为VOCs吸附剂前驱体,采用气相覆硅改性方法对其表面结构进行调控。研究结果表明,改性Y分子筛结晶度为81%,孔径基本保持不变,比表面积仅下降8.1%;其对不同VOCs分子吸附容量相差不大,具有疏水性和广谱吸附性;在脱附功率800 W微波作用下脱附15 min后,4种典型VOCs分子在改性Y分子筛上均能较为彻底地完成脱附,脱附率能达到89%以上。

【Abstract】 In view of the problem of poor performance of conventional Y zeolites in adsorbing VOCs under high humidity conditions, the conventional Y zeolites was used as the precursor of VOCs adsorbent, and its surface structure was adjusted by the gas phase silicon-coated modification method. The research results showed that the crystallinity of the modified Y zeolites was 81%, the pore size remained basically unchanged, and the specific surface area only decreased by 8.1%. Also, its adsorption capacity of different VOCs was not much different, with hydrophobicity and broad-spectrum adsorption. After desorption for 15 min under the desorption power of 800 W microwave, four typical VOCs molecules could be completely desorbed on the modified Y zeolites, and the desorption rate could reach more than 89%.

  • 【文献出处】 煤化工 ,Coal Chemical Industry , 编辑部邮箱 ,2020年04期
  • 【分类号】X701;TQ424.25
  • 【被引频次】6
  • 【下载频次】299
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