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稀土微合金化对热管用无氧铜管坯成分及组织的影响

Effects of Microalloying with Rare Earth on Composition and Microstructure of Oxygen-free Copper Tube Blank for Heat Pipe

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【作者】 陈岩陈进方汤晓水余琪王松伟张士宏曾延琦

【Author】 CHEN Yan;CHEN Jin-fang;TANG Xiao-shui;YU Qi;WANG Song-wei;ZHANG Shi-hong;ZENG Yan-qi;Jiangxi Copper Co., Ltd.;Jiangxi Copper Technology Research Academy Co., Ltd.;Institute of Metal Research, Chinese Academy of Sciences;JCC Processing Business Division;

【机构】 江西铜业集团有限公司江西铜业技术研究院有限公司中国科学院金属研究所江西铜业加工事业部

【摘要】 目的解决连铸连轧无氧铜管坯成分与组织控制问题。方法通过稀土净化除杂与微合金化作用,对无氧铜熔铸成分控制、水平连铸和行星轧制工艺开展深入研究。结果稀土添加后铸坯中P的质量分数由添加前0.009 5%降低至0.001 45%~0.001 82%,降低了80.8%;O的质量分数由0.004 5%降低至0.001 3%~0.001 83%,降低了59.3%;铸坯晶粒尺寸由稀土添加前的2200μm细化到到650μm,细化了70.4%;三辊行星组织轴向平均晶粒为16μm,周向平均晶粒为21μm。结论稀土微合金化能够有效控制热管用无氧铜铸坯的成分;稀土微合金化明显细化了铸坯的晶粒组织,使无氧铜轧制变形组织更加均匀。

【Abstract】 The work aims to solve the problems on controlling composition and microstructure of oxygen-free copper tubes by continuous casting and rolling. The controlling of cast composition, horizontal continuous casting and planetary rolling process of oxygen-free copper tube were studied in-depth by purification and microalloying with rare earth. The results showed that the mass fraction of P and O in the casting blank added with rare earth was reduced from 0.0095% to 0.001 45%-0.001 82% by 80.8% and from 0.004 5% to 0.001 3%-0.001 83% by 59.3% respectively. Moreover, the grain size of cashing blank added with rare earth was refined from 2200 μm to 650 μm by 70.4%. The axial average grain size of the three-roller planetary structure was 16 μm and the circumferential average grain size was 21 μm. The microalloying with rare earth can effectively control the composition of the oxygen-free copper for heat pipe. It apparently refines the grain size structure and makes the deformation microstructure of oxygen-free copper rolling more uniform.

【关键词】 热管稀土无氧铜成分组织
【Key words】 heat piperare earthoxygen-free coppercompositionmicrostructure
【基金】 中国博士后科学基金(2019M662276);中国科学院科技服务网络计划区域重点资助项目(KFJ-STS-QYZD-145)
  • 【文献出处】 精密成形工程 ,Journal of Netshape Forming Engineering , 编辑部邮箱 ,2020年06期
  • 【分类号】TG146.11
  • 【被引频次】2
  • 【下载频次】110
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