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可溶性离子对煅烧烟气脱硫石膏水化的影响(英文)

Effects of Soluble Ions on Hydration of Calcined Flue Gas Desulphurization Gypsum

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【作者】 林福星钟晏池鄢树枫林碧凡王建华苏志忠

【Author】 Fu-xing Lin;Yan-chi Zhong;Shu-feng Yan;Bi-fan Lin;Jian-hua Wang;Zhi-zhong Su;College of Resources and Chemical Engineering, Sanming University;Fujian Engineering Research Center for Advanced Fluorine-containing Materials;CAS Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering,University of Science and Technology of China;

【通讯作者】 林福星;苏志忠;

【机构】 三明学院资源与化工学院福建省氟新材料工程研究中心中国科学技术大学高分子科学与工程系中国科学院软物质化学重点实验室

【摘要】 本文主要研究了不同水溶性离子对煅烧烟气脱硫石膏水化过程,也就是对大块煅烧石膏向石膏转化的相变过程的影响.研究表明,在煅烧石膏向石膏转化的相变过程中,所有的阳离子都能加速煅烧石膏的水化作用,其中Ca2+的加速效应最弱.对于最终沉淀得到的晶体,除了钠离子外,晶体尺寸不受不同种类盐的影响.而在钠离子中,可以观察到长度大于130μm的巨型结晶.本研究阐明了不同离子对煅烧石膏水化的影响,为原始的烟气脱硫石膏在实际应用前的预处理提供了充分的指导.

【Abstract】 The influence of various water soluble cations(K+, Na+, Ca2+, Mg2+) on the hydration of calcined flue gas desulphurization gypsum was investigated. The results show that all cations but Ca2+ can accelerate the hydration of bassanite. The final crystal size is not largely influenced by different salts, except for Na+, where the giant crystal with length of>130 μm is observed. Current study clarifies the influence of different ions on the hydration of bassanite, which could provide sufficient guide for the pre-treatment of original flue gas desulphurization gypsum before actual application.

【关键词】 烧石膏烟气脱硫水化可溶性离子
【Key words】 BassaniteFlue gas desulphurizationHydrationSoluble ions
【基金】 supported by the National Natural Science Foundation of China (No.51473152);Scientific research foundation for Young Talents from Fujian Provincial Department of Education (No.JT180494);Start-up Foundation for Advanced Talents in Sanming University (No.18YG07);Industry-University-Research Cooperation Fund from Sanming Institute of Fluorine Chemical Industry Technology (FCIT20180105);Scientific research Platform Construction Pproject from Fujian Provincial Department of Science and Technology (No.2018H2002)
  • 【文献出处】 Chinese Journal of Chemical Physics ,化学物理学报(英文版) , 编辑部邮箱 ,2020年06期
  • 【分类号】TQ177.375
  • 【被引频次】2
  • 【下载频次】156
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